Foundations of Colloid Science, Volume 2Clarendon Press, 1987 - Colloids |
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Page 882
... free energy change , AF , which is needed to calculate the potential energy due to van der Waals forces ( VH ) between the approaching phases . ( We use н ( for Hamaker ) rather than the conventional A ( for attraction ) because these ...
... free energy change , AF , which is needed to calculate the potential energy due to van der Waals forces ( VH ) between the approaching phases . ( We use н ( for Hamaker ) rather than the conventional A ( for attraction ) because these ...
Page 927
... free energy can then be written : F " = F " + F " + F1⁄2 TS " ( config ) . - ( 16.5.3 ) Note that this expression cannot be derived from purely thermodynamic considerations . It follows from a statistical mechanical examination of how the ...
... free energy can then be written : F " = F " + F " + F1⁄2 TS " ( config ) . - ( 16.5.3 ) Note that this expression cannot be derived from purely thermodynamic considerations . It follows from a statistical mechanical examination of how the ...
Page 1084
... free energy 249 ; see also Helmholtz free energy spectroscopy of micellar solutions 600 spectrum , absorption 196 sphere , light scattering 155f , 829–71 , 982f spheres , electrical d.l. on 389 , 790 , 804 , 817 interaction between 182 ...
... free energy 249 ; see also Helmholtz free energy spectroscopy of micellar solutions 600 spectrum , absorption 196 sphere , light scattering 155f , 829–71 , 982f spheres , electrical d.l. on 389 , 790 , 804 , 817 interaction between 182 ...
Contents
Contents of Volume I ix | 675 |
ADSORPTION FROM SOLUTION | 709 |
CHARACTERIZATION OF COLLOIDAL DISPERSIONS 1 | 710 |
Copyright | |
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Foundations of Colloid Science. Vol. 1-2. Collab. Lee R. White, Leonard R ... No preview available - 1992 |
Common terms and phrases
adsorbed adsorption approximation assumed behaviour bulk C-potential calculated Chapter Chem co-surfactant coagulation coalescence Colloid interface Sci colloidal dispersions compare with eqn component constant corresponding counterions diffuse dilute double layer droplets effect electrical electrokinetic electrolyte electrolyte concentration electrostatic emulsion equilibrium Establish eqn estimate Exercise experimental Faraday ferrofluid field film flow fluid force free energy given hard sphere head group Hunter hydrophilic increases interaction K₁ latex liquid measured micelles microemulsion molecules neutron neutron scattering Newtonian fluid non-ionic surfactant Note obtained occur Ottewill Overbeek parameters particles phase Phys Poisson-Boltzmann equation polymer potential potential determining ions pressure procedure pseudoplastic radius region repulsion result scattering shear rate shear stress shown in Fig solution specific adsorption spherical stability structure surface charge surfactant suspension temperature thermodynamic thin thixotropic values velocity visco-elastic viscometer viscosity volume fraction Waals zero