Foundations of colloid science, Volume 2 |
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Page 750
12.4.3 Establish eqn (12.4.19), using Exercise (12.4.2). [Hint: To establish (12.4.
19) first show that Hb = exp(V)N + v); *1C£, = exp(A - n); *K£ = exp(-A-n).] 12.4.4
Use the following set of parameters in the amphoteric site binding model to
obtain ...
12.4.3 Establish eqn (12.4.19), using Exercise (12.4.2). [Hint: To establish (12.4.
19) first show that Hb = exp(V)N + v); *1C£, = exp(A - n); *K£ = exp(-A-n).] 12.4.4
Use the following set of parameters in the amphoteric site binding model to
obtain ...
Page 776
The parameter YA is a reduced potential ( = !FipA/RT) where ipA is the potential
in the plane of adsorption. Koopal argues that this formulation is more consistent
thermodynamically because it separates the ideal adsorption behaviour from the
...
The parameter YA is a reduced potential ( = !FipA/RT) where ipA is the potential
in the plane of adsorption. Koopal argues that this formulation is more consistent
thermodynamically because it separates the ideal adsorption behaviour from the
...
Page 860
The ionic strength and volume fractions are known experimental parameters, and
the surface potential in this system was evaluated by extensive computer
simulation modelling of the data (van Megen and Snook 1977). Further, the
particle ...
The ionic strength and volume fractions are known experimental parameters, and
the surface potential in this system was evaluated by extensive computer
simulation modelling of the data (van Megen and Snook 1977). Further, the
particle ...
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Contents
INTRODUCTION TO STATISTICAL MECHANICS | 675 |
ADSORPTION FROM SOLUTION | 709 |
THE ELECTROKINETIC EFFECTS | 786 |
Copyright | |
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adsorbed adsorption approximation assumed behaviour bulk calculated Chapter Chem co-surfactant coagulation coalescence Colloid interface Sci colloidal dispersion colloidal particles compare with eqn component constant correlation function corresponding counterions curve diameter diffuse dilute double layer droplets effect electrical electrokinetic electrolyte electrolyte concentration electrostatic emulsion equilibrium Establish eqn estimate Exercise experimental Faraday ferrofluid field film flow fluid force free energy given hard sphere head group Hunter hydrophilic increases interaction latex liquid magnetic measured micelles microemulsion molecules neutron Newtonian fluid non-ionic surfactant Note obtained occur Ottewill Overbeek pair parameters phase Phys plane Poisson-Boltzmann equation polymer potential potential determining ions pressure procedure pseudoplastic radius region repulsion result scattering shear rate shear stress shown in Fig solution specific adsorption spherical stability surface charge surfactant suspension temperature thermodynamic thin thixotropic values velocity visco-elastic viscometer viscosity volume fraction Waals zero