Foundations of Colloid Science, Volume 2 |
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Page 677
The interaction only depends on the separation between the centres of the
molecules . At large separations , r > o , the interaction is attractive , u ( r ) < 0 .
For monatomic molecules. u ( r ) ] Fig . 11 . 2 . 1 . The interaction energy between
two ...
The interaction only depends on the separation between the centres of the
molecules . At large separations , r > o , the interaction is attractive , u ( r ) < 0 .
For monatomic molecules. u ( r ) ] Fig . 11 . 2 . 1 . The interaction energy between
two ...
Page 678
For monatomic molecules this is due to the London - van der Waals attraction ,
which falls off with separation liker ( Chapter 4 ) . At small separations , overlap of
the electron orbitals of the two molecules gives rise to a repulsion which ...
For monatomic molecules this is due to the London - van der Waals attraction ,
which falls off with separation liker ( Chapter 4 ) . At small separations , overlap of
the electron orbitals of the two molecules gives rise to a repulsion which ...
Page 685
... the average force between two molecules separated by a distance r ( averaged
over all configurations of the rest of the ... then the reversible work , W ( r ) needed
to move the two molecules from a large separation to some separation r is just ...
... the average force between two molecules separated by a distance r ( averaged
over all configurations of the rest of the ... then the reversible work , W ( r ) needed
to move the two molecules from a large separation to some separation r is just ...
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Contents
INTRODUCTION TO STATISTICAL MECHANICS | 675 |
ADSORPTION FROM SOLUTION | 709 |
THE ELECTROKINETIC EFFECTS | 786 |
Copyright | |
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Common terms and phrases
adsorbed adsorption applied approach approximation assumed average becomes behaviour bulk calculated Chapter charge Chem Colloid interface Sci colloidal component concentration constant correlation corresponding density depends described determined developed direction discussed dispersion distance double layer droplets effect electrical electrokinetic electrolyte emulsion energy equation equilibrium estimate et al example Exercise experimental expression factor field film flow fluid force fraction function given gives groups important increases interaction interface involved ions limit liquid material measured microemulsion molecules Note observed obtained occur pair particles phase positive possible potential present pressure problem procedure radius range reduces referred region result scattering Section separation shear rate shown solution specific spheres stability stress structure surface surface charge surface tension suspension temperature theory thin usually values viscosity volume zero