Foundations of Colloid Science, Volume 1Liquid suspension systems are the basic ingredients of paints, detergents, biological cells, and countless other systems of scientific and technological importance. This book presents the fundamental physical and chemical concepts necessary to the understanding of these systems and of colloid science in general. New ideas are introduced carefully and formulae are developed in full, with exercises to help the reader throughout. The frequent references to the many applications of colloid science will be especially helpful to beginning research scientists and people in industry, medicine and agriculture who often find their training in this area inadequate. Integrating developments from the time of colloid science's infancy forty years ago to its present state as a rigorous discipline, this intelligently assembled work elucidates a remarkable range of concepts, techniques, and behaviors. |
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Page 464
... stabilization Stabilization AGF AHF ASF AHF / TASF | type Flocculation ≥0 + ≥1 enthalpic heating to UCFT ≥0 ≥0 ≤1 entropic cooling to LCFT ≤1 combined not access- enthalpic- ible entropic change can be resolved into its respective ...
... stabilization Stabilization AGF AHF ASF AHF / TASF | type Flocculation ≥0 + ≥1 enthalpic heating to UCFT ≥0 ≥0 ≤1 entropic cooling to LCFT ≤1 combined not access- enthalpic- ible entropic change can be resolved into its respective ...
Page 465
... stabilization on an enthalpy - entropy diagram . This corresponds to enthalpic stabilization ( see Table 8.5 ) . Conversely , ASF for a sterically stabilized ... stabilized dispersions at room THERMODYNAMIC BASIS OF STERIC STABILIZATION 465.
... stabilization on an enthalpy - entropy diagram . This corresponds to enthalpic stabilization ( see Table 8.5 ) . Conversely , ASF for a sterically stabilized ... stabilized dispersions at room THERMODYNAMIC BASIS OF STERIC STABILIZATION 465.
Page 466
... stabilization is more common than enthalpic stabilization in non - aqueous dispersion media . Indeed , the high incidence of entropic stabilization under these conditions has sometimes led to the mistaken belief that all sterically ...
... stabilization is more common than enthalpic stabilization in non - aqueous dispersion media . Indeed , the high incidence of entropic stabilization under these conditions has sometimes led to the mistaken belief that all sterically ...
Contents
CHARACTERIZATION OF COLLOIDAL | 1 |
BEHAVIOUR OF COLLOIDAL DISPERSIONS | 49 |
PARTICLE SIZE AND SHAPE | 104 |
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adsorbed adsorption aggregation approximation aqueous assumed behaviour Brownian motion bulk calculated capillary Chem chemical chemical potential coagulation coefficient Colloid interface Sci colloid science colloidal dispersions colloidal particles component constant contact angle crystal curvature curve density determined dielectric diffuse dipole distance distribution DLVO theory double layer droplet effect electrolyte electron electrostatic enthalpic entropy equation equilibrium Establish eqn Exercise experimental flocculation flow fluid force free energy frequency function given head group hydrocarbon interaction energy ions liquid material measured method micelle microscope molar mass molecular molecules monomer negative Note obtained occurs Overbeek phase plates polymer potential energy procedure quantity R₁ radius region repulsion result scattering sedimentation separation shear silver iodide solid solution solvent spheres spherical stabilizing moieties steric stabilization stress surface tension surfactant suspension temperature term theory thermodynamic vector velocity viscosity volume Waals x₁ Young-Laplace equation zero