Advances in Elastomers and Rubber ElasticityThe present book is a sequel to "Elastomers and Rubber Elasticity," edited by J.E. Mark and J. Lal and published by the American Chemical Society in 1982. It is also based on papers presented at an ACS Symposium, sponsored by the Division of Polymer Chemistry, Inc., in this case one held in Chicago in September of 1985. The keynote speaker was to have been Pro fessor Paul J. Flory, and his untimely death just prior to the symposium was a tremendous loss to all of polymer science, in particular to those in terested in elastomeric materials. It is to his memory that this book is dedicated. There has been a great deal of progress in preparing and studying elas tomers since the preceding symposium, which was in 1981. In the case of the synthesis and curing of elastomers, much of the background necessary to an appreciation of these advances is given in the first, introductory chapter. |
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Results 1-5 of 26
Page 13
... III IV ( e.g. , polystyrene ) and short while the B blocks are flexible ( e.g. , 1,4 - polyisoprene ) and long . Such block copolymers , referred to as thermoplastic elastomers , behave as elastomers at ambient temperatures but 13.
... III IV ( e.g. , polystyrene ) and short while the B blocks are flexible ( e.g. , 1,4 - polyisoprene ) and long . Such block copolymers , referred to as thermoplastic elastomers , behave as elastomers at ambient temperatures but 13.
Page 14
Joginder Lal, James E. Mark. thermoplastic elastomers , behave as elastomers at ambient temperatures but are thermoplastic at elevated temperatures where fabrication is accomplished . The dual behavior of thermoplastic elastomers results ...
Joginder Lal, James E. Mark. thermoplastic elastomers , behave as elastomers at ambient temperatures but are thermoplastic at elevated temperatures where fabrication is accomplished . The dual behavior of thermoplastic elastomers results ...
Page 15
... thermoplastic elastomer . A variation of this multiblock copolymer is the polyester - polyurethane system in which the diol prepolymer is produced by polyesterification . The growing importance of thermoplastic elastomers is clearly ...
... thermoplastic elastomer . A variation of this multiblock copolymer is the polyester - polyurethane system in which the diol prepolymer is produced by polyesterification . The growing importance of thermoplastic elastomers is clearly ...
Page 52
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Contents
| 1 | |
| 17 | |
| 37 | |
Polyurethane Elastomers with Monodisperse Segments | 51 |
Relationship Between Chemical Composition and Hysteresis | 89 |
Morphology and Properties of Segmented Polyurethane | 103 |
Diene Triblock Polymers with StyreneAlphaMethylstyrene | 129 |
PhaseSelective Curing of Poly pMethylstyrenebButadienebp | 143 |
The Statistical Mechanics of Entangled Networks | 269 |
Calculation of Molecular Deformation and Orientation | 279 |
Rubber Elasticity Entanglement Constraints and | 291 |
StrainInduced Crystallization in Rubbers | 303 |
StressTemperature Behavior of Stretched TransPolyisoprene | 315 |
Intramolecular Reaction and Network Properties | 329 |
The Hydrosilylation Cure of Polyisobutene | 347 |
The Elastic Behavior of Cis14Polybutadiene | 361 |
A New Free Radical Approach to the Synthesis | 157 |
An Overview of the Chemical Modification of Natural Rubber | 175 |
Stabilisation of Rubbers in Aggressive Environments | 189 |
Polymers from Hydrogenated Polydienes Prepared | 197 |
A New Crosslinking Reaction of Polyacrylic Elastomer | 221 |
Fatigue Resistance of Polybutadienes and Effect | 233 |
The Influence of Chemical Structure on the Strength | 253 |
Optical Studies of Network Topology | 379 |
Theory of Segmental Orientation in Amorphous Polymer | 393 |
Study of the Uniaxial Deformation of Rubber Network | 407 |
Nonlinear Strain Measures of Rubber Networks and Polymer Melts | 421 |
Index | 435 |
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Common terms and phrases
affine anionic antioxidant behavior block polymers butadiene calculated catalyst CH₂ chain end CHDI Chem chemical crosslinking crystalline crystallites crystallization curing curves cyclohexane deformation density diene dynamic mechanical effect elasticity elongation end block entanglements equation equilibrium experimental fatigue Flory fraction function glass transition temperature groups hard segment content hard segment length higher hydrogenated hydrosilylation increase initiator intramolecular reaction isoprene Macromolecules measurements melting temperature microstructure modulus molecular weight molecules monodisperse monomer observed obtained oligomers orientation PDMS peak phantom network phase Phys polybutadiene polyether polyisoprene polymerization polystyrene polyurethane-ureas polyurethanes prepared prepolymer PTMO rubber sample scattering segment length distribution shown in Figure soft segment solvent spectra strain stress stress-strain stretched structure styrene swollen synthesis Table theory thermal thermoplastic thermoplastic elastomers tion toluene triblock copolymer uniaxial values vinyl content vulcanizates