The Theory of Polymer Dynamics
This book provides a comprehensive account of the modern theory for the dynamical properties of polymer solutions. The theory has undergone dramatic evolution over the last two decades due to the introduction of new methods and concepts that have extended the frontier of theory from dilute solutions in which polymers move independently to concentrated solutions where many polymers converge. Among the properties examined are viscoelasticity, diffusion, dynamic light scattering, and electric birefringence. Nonlinear viscoelasticity is discussed in detail on the basis of molecular dynamical models. The book bridges the gap between classical theory and new developments, creating a consistent picture of polymer solution dynamics over the entire concentration range.
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STATIC PROPERTIES OF POLYMERS
1 Eigenfunctions of the Smoluchowski equation
1 The VerdierStockmayer model
IV Polarizability tensor of a Gaussian chain
1 Transformation to collective coordinates
DYNAMICS OF A POLYMER IN A FIXED NETWORK
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approximation average beads becomes behaviour Brownian motion Chem coefficient concentrated solutions condition consider constitutive equation contour length fluctuation correlation function defined deformation denotes depends diffusion constant dilute solution discussed distribution function dynamic light scattering effect end-to-end vector flexible polymers fluid form birefringence free energy Gaussian chain Gennes given by eqn gives Green function Hence hydrodynamic hydrodynamic interaction integral intrinsic viscosity isotropic Langevin equation linear Macromolecules Macromolecules 17 macroscopic molecular weight nematic nonlinear obtained orientation Osaki parameter particles Phys polarizability polymer solutions polymeric liquids potential primitive chain problem properties region relaxation modulus Reproduced from ref reptation rewritten Rheol rodlike polymers rotational diffusion Rouse model Section shear flow shear rate shear stress shown in Fig Smoluchowski equation solvent stress tensor structure factor term test polymer theory time-scale topological constraints velocity gradient viscoelasticity viscosity written Zimm model