Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Page viii
3 / THERMODYNAMICS: FIRST LAW AND THERMOCHEMISTRY 89 3-1 Energy, Work, and Heat 89 3-2 Equivalence of Energy Forms-First Law of Thermodynamics 92 3-3 Some Isothermal Physical Changes 94 34 Heat Capacity 97 3-5 Energy Changes in Chemical ...
3 / THERMODYNAMICS: FIRST LAW AND THERMOCHEMISTRY 89 3-1 Energy, Work, and Heat 89 3-2 Equivalence of Energy Forms-First Law of Thermodynamics 92 3-3 Some Isothermal Physical Changes 94 34 Heat Capacity 97 3-5 Energy Changes in Chemical ...
Page 23
The first drop of liquid appears at point b, the last bit of gas is condensed at point c, and further reduction in volume past 0 requires the application of increasingly larger pressures, consistent with the relatively low ...
The first drop of liquid appears at point b, the last bit of gas is condensed at point c, and further reduction in volume past 0 requires the application of increasingly larger pressures, consistent with the relatively low ...
Page 30
Wallace Brey. 1-9 energy expression, where the first term represents the attractive interaction and the second term corresponds to the repulsive interaction: A B. E. : —F. +. F. (1-36). In concluding the discussion of van der Waals ...
Wallace Brey. 1-9 energy expression, where the first term represents the attractive interaction and the second term corresponds to the repulsive interaction: A B. E. : —F. +. F. (1-36). In concluding the discussion of van der Waals ...
Page 49
The first nine chapters present an introductory, well-illustrated description of models of the liquid state and intermolecular forces. D. Eisenberg and W. Kauzmann, The Structure and Properties of Water, Oxford Univ.
The first nine chapters present an introductory, well-illustrated description of models of the liquid state and intermolecular forces. D. Eisenberg and W. Kauzmann, The Structure and Properties of Water, Oxford Univ.
Page 62
When this mixture is heated, the first vapor to come off has the composition Y4. This vapor can be completely condensed to a liquid, still of the same composition as Y4, at point X5. This liquid, if boiled, will initially give off vapor ...
When this mixture is heated, the first vapor to come off has the composition Y4. This vapor can be completely condensed to a liquid, still of the same composition as Y4, at point X5. This liquid, if boiled, will initially give off vapor ...
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Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero