Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Results 1-5 of 43
Page 1
... flow, but it is only with considerable difficulty that they detach themselves from intimate association with other molecules in the bulk of the liquid, as they must do if the liquid is to be vaporized. In a solid, each molecule has a ...
... flow, but it is only with considerable difficulty that they detach themselves from intimate association with other molecules in the bulk of the liquid, as they must do if the liquid is to be vaporized. In a solid, each molecule has a ...
Page 3
... flow, and finally a temperature is reached at which another change of state occurs, the formation of a vapor. Vaporization requires energy sufficient not only to pull the molecules away from one another against the forces of attraction ...
... flow, and finally a temperature is reached at which another change of state occurs, the formation of a vapor. Vaporization requires energy sufficient not only to pull the molecules away from one another against the forces of attraction ...
Page 41
... flow. In the process of flow, the molecules comprising the fluid move past one another, and viscosity arises from what can be termed the “frictional” effects of relative motion. Both liquids and gases are viscous, but the molecules of a ...
... flow. In the process of flow, the molecules comprising the fluid move past one another, and viscosity arises from what can be termed the “frictional” effects of relative motion. Both liquids and gases are viscous, but the molecules of a ...
Page 42
... flow. Such fluids are called Newtonian. For some systems containing molecules which are very large or are quite far from spherical in shape, the liquid structure is changed by the application of the force, and so the coefficient of ...
... flow. Such fluids are called Newtonian. For some systems containing molecules which are very large or are quite far from spherical in shape, the liquid structure is changed by the application of the force, and so the coefficient of ...
Page 43
... flow is great, some of the potential energy of the liquid head goes into acceleration of the liquid and not all is available for overcoming frictional resistance. The time of flow is then greater than that calculated from the Poiseuille ...
... flow is great, some of the potential energy of the liquid head goes into acceleration of the liquid and not all is available for overcoming frictional resistance. The time of flow is then greater than that calculated from the Poiseuille ...
Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero