Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Page 3
If benzene and water, which do not dissolve very well in one another, are mixed together, there form two liquid phases separated by a visible boundary surface. If liquid water is mixed with a relatively large amount of sodium chloride ...
If benzene and water, which do not dissolve very well in one another, are mixed together, there form two liquid phases separated by a visible boundary surface. If liquid water is mixed with a relatively large amount of sodium chloride ...
Page 26
... Hydrogen sulfide 0.93 9.1 (— 78.5°) Hydrogen bromide 0.80 7.0 (—85°) Toluene 0.39 2.4 Benzene 0 2.27 Carbon tetrachloride 0 2.23 “Temperature is 25°C unless otherwise indicated. u '9 Figure 1-11 Salvation of ions by oriented water.
... Hydrogen sulfide 0.93 9.1 (— 78.5°) Hydrogen bromide 0.80 7.0 (—85°) Toluene 0.39 2.4 Benzene 0 2.27 Carbon tetrachloride 0 2.23 “Temperature is 25°C unless otherwise indicated. u '9 Figure 1-11 Salvation of ions by oriented water.
Page 32
... it is often convenient to make a rough qualitative classification into those liquids that are normal, including those such as benzene, carbon tetrachloride, and paraffin hydrocarbons that have no permanent electric dipoles or only ...
... it is often convenient to make a rough qualitative classification into those liquids that are normal, including those such as benzene, carbon tetrachloride, and paraffin hydrocarbons that have no permanent electric dipoles or only ...
Page 41
Table 1-5 Surface tensions for various liquids at 20°C Surface tension Surface tension Liquid (dyn/ cm) Liquid (dyn/cm) Water 72.7 Ethyl acetate 23.8 m-Cresol 37.5 Acetone 23.5 Benzene 28.9 Ethanol 22.5 Acetic acid 27.6 n-Hexane 18.4 ...
Table 1-5 Surface tensions for various liquids at 20°C Surface tension Surface tension Liquid (dyn/ cm) Liquid (dyn/cm) Water 72.7 Ethyl acetate 23.8 m-Cresol 37.5 Acetone 23.5 Benzene 28.9 Ethanol 22.5 Acetic acid 27.6 n-Hexane 18.4 ...
Page 43
... 0.449 0.395 0.349 Ethyl alcohol 1.200 1.003 0.831 0.701 0.591 Benzene 0.647 0.561 0.492 0.436 0.339 Aniline 4.40 3.15 2.37 1.85 1.51 Mercury 1.55 1.50 1.45 1.41 1.37 1-13 it is seen that the viscosity coefficient increases with.
... 0.449 0.395 0.349 Ethyl alcohol 1.200 1.003 0.831 0.701 0.591 Benzene 0.647 0.561 0.492 0.436 0.339 Aniline 4.40 3.15 2.37 1.85 1.51 Mercury 1.55 1.50 1.45 1.41 1.37 1-13 it is seen that the viscosity coefficient increases with.
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Contents
| 1 | |
| 51 | |
| 89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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Common terms and phrases
absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero
Bibliographic information
| Title | Physical Chemistry and Its Biological Applications |
| Author | Wallace Brey |
| Publisher | Elsevier, 2012 |
| ISBN | 032314487X, 9780323144872 |
| Length | 602 pages |
| Subjects | › › Science / Chemistry / Physical & Theoretical |
| Export Citation | BiBTeX EndNote RefMan |