Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Page ix
... Cells and Electrode Potentials 215 Techniques of Potential Measurement 222 Oxidation—Reduction Titrations and Indicators 225 Characteristics of Organic Oxidation—Reduction Systems 229 Biochemical Oxidation 232 Potentiometric ...
... Cells and Electrode Potentials 215 Techniques of Potential Measurement 222 Oxidation—Reduction Titrations and Indicators 225 Characteristics of Organic Oxidation—Reduction Systems 229 Biochemical Oxidation 232 Potentiometric ...
Page 18
... cells generally involve the measurement of small volumes of CO2 produced and of O2 consumed. One of the outfits used for this purpose, known as the Warburg apparatus, is shown diagrammatically in Figure 1-9. The organism to be studied ...
... cells generally involve the measurement of small volumes of CO2 produced and of O2 consumed. One of the outfits used for this purpose, known as the Warburg apparatus, is shown diagrammatically in Figure 1-9. The organism to be studied ...
Page 32
... cells. Not only is the nature of water of critical significance in determining the nature of life processes, but also the structures of such macromolecules as proteins are governed by the existence of hydrogen bonds between neighboring ...
... cells. Not only is the nature of water of critical significance in determining the nature of life processes, but also the structures of such macromolecules as proteins are governed by the existence of hydrogen bonds between neighboring ...
Page 37
... cells, and they represent the key to many catalytic processes, as we shall see in Chapters 11 and 12. Imagine that a spherical droplet of liquid is distorted to a flattened shape so that a larger area of surface is established. Work ...
... cells, and they represent the key to many catalytic processes, as we shall see in Chapters 11 and 12. Imagine that a spherical droplet of liquid is distorted to a flattened shape so that a larger area of surface is established. Work ...
Page 66
... cells. Saturation is reached at about 20 cm3 of oxygen per 100 cm3 of blood at an oxygen partial pressure of 150 torr. The oxygen content of arterial blood corresponds to a tension of about 100 torr, and that of venous blood to about 40 ...
... cells. Saturation is reached at about 20 cm3 of oxygen per 100 cm3 of blood at an oxygen partial pressure of 150 torr. The oxygen content of arterial blood corresponds to a tension of about 100 torr, and that of venous blood to about 40 ...
Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero