Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Page v
... chemistry and to show how the methods of physical chemistry are being applied to increase our understanding of living systems. The reader should have some knowledge of organic chemistry and an acquaintance with calculus, but no very ...
... chemistry and to show how the methods of physical chemistry are being applied to increase our understanding of living systems. The reader should have some knowledge of organic chemistry and an acquaintance with calculus, but no very ...
Page viii
... Chemical Reactions 121 4-5 Dependence of Entropy on Temperature 122 4-6 Some Applications of the Entropy Functions; Entropy and Probability 123 4-7 The Free Energy Function and its Significance 128 4-8 Chemical Equilibrium 134 4-9 ...
... Chemical Reactions 121 4-5 Dependence of Entropy on Temperature 122 4-6 Some Applications of the Entropy Functions; Entropy and Probability 123 4-7 The Free Energy Function and its Significance 128 4-8 Chemical Equilibrium 134 4-9 ...
Page x
Wallace Brey. 10. /. KINETICS. OF. CHEMICAL. REACTIONS 338 10-1 Rates and their Measurement 338 10-2 Kinetics of the Overall Reaction 339 10-3 Reaction Orders and Rate Constants 341 10-4 Complex Reactions 348 10-5 Chain Reactions 352 10-6 ...
Wallace Brey. 10. /. KINETICS. OF. CHEMICAL. REACTIONS 338 10-1 Rates and their Measurement 338 10-2 Kinetics of the Overall Reaction 339 10-3 Reaction Orders and Rate Constants 341 10-4 Complex Reactions 348 10-5 Chain Reactions 352 10-6 ...
Page 16
... chemical nature of the molecules comprising the gas. In a mixture of gases that separately behave ideally we expect to find no distinction among the different kinds of molecules. In fact, even if the separate components of a gaseous ...
... chemical nature of the molecules comprising the gas. In a mixture of gases that separately behave ideally we expect to find no distinction among the different kinds of molecules. In fact, even if the separate components of a gaseous ...
Page 49
... Chemical Calculations,” J. Chem. volume, mole fraction, and percent by weight of CO2 in the expired air. 25. At 50°C, a volume of 40.0 liters of inert gas under a pressure of 1 atm is bubbled through liquid bromobenzene of which the ...
... Chemical Calculations,” J. Chem. volume, mole fraction, and percent by weight of CO2 in the expired air. 25. At 50°C, a volume of 40.0 liters of inert gas under a pressure of 1 atm is bubbled through liquid bromobenzene of which the ...
Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero