Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Page 3
If liquid water is mixed with a relatively large amount of sodium chloride so that not all the salt dissolves, the two phases present after equilibrium is reached are saturated aqueous salt solution and solid sodium chloride.
If liquid water is mixed with a relatively large amount of sodium chloride so that not all the salt dissolves, the two phases present after equilibrium is reached are saturated aqueous salt solution and solid sodium chloride.
Page 25
In the sodium chloride crystal, each sodium ion is surrounded by six chloride ions and each chloride ion by six sodium ions, and the energy of each positive—negative interaction between a pair of nearest neighbors is substantially ...
In the sodium chloride crystal, each sodium ion is surrounded by six chloride ions and each chloride ion by six sodium ions, and the energy of each positive—negative interaction between a pair of nearest neighbors is substantially ...
Page 26
... (170°) Hydrogen fluoride 1.91 84 (0°) Ethylenediamine 1.90 142 Water 1.85 78.5 Bromobenzene 1.70 5.4 Ethanol 1.68 24.3 Methanol 1.66 32.6 Sulfur dioxide 1.60 14.1 (20°) Ammonia ~ 1.47 16.9 Hydrogen chloride 1.03 4.6 Chloroform 1.15 ...
... (170°) Hydrogen fluoride 1.91 84 (0°) Ethylenediamine 1.90 142 Water 1.85 78.5 Bromobenzene 1.70 5.4 Ethanol 1.68 24.3 Methanol 1.66 32.6 Sulfur dioxide 1.60 14.1 (20°) Ammonia ~ 1.47 16.9 Hydrogen chloride 1.03 4.6 Chloroform 1.15 ...
Page 29
... but the total interaction energy is about 10 times as large as it is in hydrogen chloride aside from the effects of the hydrogen bond, which may also be present in HCl. The contributions at room temperature to the HCl interaction ...
... but the total interaction energy is about 10 times as large as it is in hydrogen chloride aside from the effects of the hydrogen bond, which may also be present in HCl. The contributions at room temperature to the HCl interaction ...
Page 30
For example, water has a boiling point about 142 K higher than the boiling point of hydrogen sulfide, a substance with a greater molecular weight, and hydrogen fluoride boils more than 100 K above hydrogen chloride.
For example, water has a boiling point about 142 K higher than the boiling point of hydrogen sulfide, a substance with a greater molecular weight, and hydrogen fluoride boils more than 100 K above hydrogen chloride.
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Contents
| 1 | |
| 51 | |
| 89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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Common terms and phrases
absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero
Bibliographic information
| Title | Physical Chemistry and Its Biological Applications |
| Author | Wallace Brey |
| Publisher | Elsevier, 2012 |
| ISBN | 032314487X, 9780323144872 |
| Length | 602 pages |
| Subjects | › › Science / Chemistry / Physical & Theoretical |
| Export Citation | BiBTeX EndNote RefMan |