Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Results 1-5 of 51
Page viii
... Coefficients of Ions 155 5-3 Conductance 165 54 Enthalpies of Solution and of Reaction of Ions 173 5-5 Ionic Hydration and the Lyotropic Series 176. 6/ACID-BASE. EQUILIBRIA. 181. 6-1 Bronsted-Lowry Concept of Acids and Bases 181 6-2 Aqueous ...
... Coefficients of Ions 155 5-3 Conductance 165 54 Enthalpies of Solution and of Reaction of Ions 173 5-5 Ionic Hydration and the Lyotropic Series 176. 6/ACID-BASE. EQUILIBRIA. 181. 6-1 Bronsted-Lowry Concept of Acids and Bases 181 6-2 Aqueous ...
Page 21
... coefficients and depend upon the temperature but not upon the pressure. The validity of this equation is based upon its ... coefficient B is found to be equivalent to b — a/PV and thus to represent the excess of the effect of volume ...
... coefficients and depend upon the temperature but not upon the pressure. The validity of this equation is based upon its ... coefficient B is found to be equivalent to b — a/PV and thus to represent the excess of the effect of volume ...
Page 42
... coefficient of viscosity 1; of the fluid. These relations are expressed in the equation _nuA _ r F (1-48) For many simple liquids and almost all gases, the coefficient of viscosity is found to have a constant numerical value at a ...
... coefficient of viscosity 1; of the fluid. These relations are expressed in the equation _nuA _ r F (1-48) For many simple liquids and almost all gases, the coefficient of viscosity is found to have a constant numerical value at a ...
Page 43
... coefficients is 5 : pi' (1-50) 112 P2t2 Several errors may enter into a viscosity determination by the Ostwald method ... coefficient increases with. n-Octane 0.542 0.483 0.433 — 0.355 1. A mixture of gases containing 24.0 g of C0,,. 1-12 ...
... coefficients is 5 : pi' (1-50) 112 P2t2 Several errors may enter into a viscosity determination by the Ostwald method ... coefficient increases with. n-Octane 0.542 0.483 0.433 — 0.355 1. A mixture of gases containing 24.0 g of C0,,. 1-12 ...
Page 44
Wallace Brey. 1-13 it is seen that the viscosity coefficient increases with increasing molecular size. It is noted also that associated liquids have, in general, viscosity coefficients larger than those of normal liquids. For any liquid ...
Wallace Brey. 1-13 it is seen that the viscosity coefficient increases with increasing molecular size. It is noted also that associated liquids have, in general, viscosity coefficients larger than those of normal liquids. For any liquid ...
Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero