Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Page vii
... Colligative Properties—Vapor Pressure Lowering 72 Freezing Point Depression and Boiling Point Elevation 74 Osmotic Pressure 79 Partial Molar Volume 84 3 / THERMODYNAMICS: FIRST LAW AND THERMOCHEMISTRY 89 3-1 Energy,. vii Table of Contents.
... Colligative Properties—Vapor Pressure Lowering 72 Freezing Point Depression and Boiling Point Elevation 74 Osmotic Pressure 79 Partial Molar Volume 84 3 / THERMODYNAMICS: FIRST LAW AND THERMOCHEMISTRY 89 3-1 Energy,. vii Table of Contents.
Page 72
... COLLIGATIVE. PROPERTIES. —. VAPOR. PRESSURE. LOWERING. In a solution in which the solutes are nonvolatile, only the solvent contributes measurably to the vapor pressure. However, the presence of ... Colligative Properties—Vapor Pressure ...
... COLLIGATIVE. PROPERTIES. —. VAPOR. PRESSURE. LOWERING. In a solution in which the solutes are nonvolatile, only the solvent contributes measurably to the vapor pressure. However, the presence of ... Colligative Properties—Vapor Pressure ...
Page 73
... /1000, leading to. (2-14). (2-15) mM. 2. T. 10001. (2'16). Combining this with Equation (2-13) results in o _ Pl p _ li p? T 1000 Example: A portion of 1.25 g of a solute dissolved. 2-7 COLLIGATIVE PROPERTIES—VAPOR PRESSURE LOWERING 73.
... /1000, leading to. (2-14). (2-15) mM. 2. T. 10001. (2'16). Combining this with Equation (2-13) results in o _ Pl p _ li p? T 1000 Example: A portion of 1.25 g of a solute dissolved. 2-7 COLLIGATIVE PROPERTIES—VAPOR PRESSURE LOWERING 73.
Page 74
... colligative properties of dilute solutions that involve phase equilibria. The first of these is depression of the freezing point of a pure solvent by a solute. It is assumed that the solution of interest is sufficiently dilute and of ...
... colligative properties of dilute solutions that involve phase equilibria. The first of these is depression of the freezing point of a pure solvent by a solute. It is assumed that the solution of interest is sufficiently dilute and of ...
Page 76
... colligative properties, it is customary to express the concentration of the solution on the molal scale rather than on the mole fraction scale. Use of the approximation of Equation (2-16) for dilute solutions, and rearrangement, leads ...
... colligative properties, it is customary to express the concentration of the solution on the molal scale rather than on the mole fraction scale. Use of the approximation of Equation (2-16) for dilute solutions, and rearrangement, leads ...
Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero