Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Page vii
... Measurement of Gases 16 Real Gases 19 Continuity of States; Corresponding States 21 Intermolecular Forces 24 The Hydrogen Bond 30 Vapor Pressure 32 Surface Tension 37 Viscosity 41 Structure of Liquids 44 2/ SOLUTIONS OF ...
... Measurement of Gases 16 Real Gases 19 Continuity of States; Corresponding States 21 Intermolecular Forces 24 The Hydrogen Bond 30 Vapor Pressure 32 Surface Tension 37 Viscosity 41 Structure of Liquids 44 2/ SOLUTIONS OF ...
Page 9
The dimensions, and therefore the units, of the PV product are those of work or energy, and R, which by the ideal gas equation equals PV/nT, has units corresponding to work per mole per degree. NUMERICAL VALUES OF R Although the ...
The dimensions, and therefore the units, of the PV product are those of work or energy, and R, which by the ideal gas equation equals PV/nT, has units corresponding to work per mole per degree. NUMERICAL VALUES OF R Although the ...
Page 10
The atmosphere as a unit of pressure is defined directly to be 101,325 N/mz, and the torr, corresponding approximately to 1 mm of mercury, is 1/760 atm. If we multiply the value for 1 atm by the value of the gas constant in m3 atm/(mol ...
The atmosphere as a unit of pressure is defined directly to be 101,325 N/mz, and the torr, corresponding approximately to 1 mm of mercury, is 1/760 atm. If we multiply the value for 1 atm by the value of the gas constant in m3 atm/(mol ...
Page 19
... the correction term, and, in Equation (1-24), the quantity in brackets which includes pressure corresponds to Pi. ... two molecules in a certain volume at the surface and two in the corresponding volume in the interior of the gas; ...
... the correction term, and, in Equation (1-24), the quantity in brackets which includes pressure corresponds to Pi. ... two molecules in a certain volume at the surface and two in the corresponding volume in the interior of the gas; ...
Page 21
CORRESPONDING. STATES. In considering further the behavior of a real gas as distinguished from that of an ideal gas, it is profitable to extend the examination of pressure—volume—temperature relations to temperatures low enough and to ...
CORRESPONDING. STATES. In considering further the behavior of a real gas as distinguished from that of an ideal gas, it is profitable to extend the examination of pressure—volume—temperature relations to temperatures low enough and to ...
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Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero