Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Results 1-5 of 8
Page 5
The zero of temperature on the centigrade, or Celsius, scale was formerly defined
as the freezing point of water; this ice point is not the same as the triple point but
is the temperature at which ice and air-saturated water are in equilibrium under ...
The zero of temperature on the centigrade, or Celsius, scale was formerly defined
as the freezing point of water; this ice point is not the same as the triple point but
is the temperature at which ice and air-saturated water are in equilibrium under ...
Page 26
The magnitude of the permanent separation of charge in a molecule can be
expressed by a quantity known as the dipole moment; this is defined as the
product of the amount of charge separated and the dis— tance of separation.
Since the ...
The magnitude of the permanent separation of charge in a molecule can be
expressed by a quantity known as the dipole moment; this is defined as the
product of the amount of charge separated and the dis— tance of separation.
Since the ...
Page 89
Indeed, energy is best defined as the capacity to do work, or that which may be
produced from or converted into work. Heat is the term applied to energy
transferred from one place to another because of a temperature difference
between the ...
Indeed, energy is best defined as the capacity to do work, or that which may be
produced from or converted into work. Heat is the term applied to energy
transferred from one place to another because of a temperature difference
between the ...
Page 91
In order that one can think clearly about these changes in energy, it is necessary
to define precisely that portion of the universe which is under consideration. That
is, it is necessary to set up the limits or boundaries of a thermodynamic system.
In order that one can think clearly about these changes in energy, it is necessary
to define precisely that portion of the universe which is under consideration. That
is, it is necessary to set up the limits or boundaries of a thermodynamic system.
Page 94
PHASE CHANGES A simple type of physical process, the vaporization of a liquid,
affords us a first example of the application of the thermodynamic quantities that
have been defined. This change can be readily carried out at constant pressure,
...
PHASE CHANGES A simple type of physical process, the vaporization of a liquid,
affords us a first example of the application of the thermodynamic quantities that
have been defined. This change can be readily carried out at constant pressure,
...
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Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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Common terms and phrases
absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero