Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Page 17
A third way of specifying the concentration of a component of a mixture, suitable whether the mixture be gaseous, liquid, or solid, is in terms of its mole fraction. This is defined as the fraction that the number of moles of any ...
A third way of specifying the concentration of a component of a mixture, suitable whether the mixture be gaseous, liquid, or solid, is in terms of its mole fraction. This is defined as the fraction that the number of moles of any ...
Page 24
If this equation is obeyed, two substances existing at the temperatures and pressures that are the same fraction of ... when compared with each other at temperatures that are equal fractions of their respective critical temperatures, ...
If this equation is obeyed, two substances existing at the temperatures and pressures that are the same fraction of ... when compared with each other at temperatures that are equal fractions of their respective critical temperatures, ...
Page 31
... hydrogen bonding: /O—CH2—CH3 H CH,—cn,—o'\ n The size of the aggregates, as well as the fraction of the total number of H \ Figure 1-13 Q Schematic arrangement of hydrogen bonds H/ \\ between water molecules. ,// \\ H H ...
... hydrogen bonding: /O—CH2—CH3 H CH,—cn,—o'\ n The size of the aggregates, as well as the fraction of the total number of H \ Figure 1-13 Q Schematic arrangement of hydrogen bonds H/ \\ between water molecules. ,// \\ H H ...
Page 42
... cause two parallel planes of 1 cm2 area 1 cm apart in the liquid to slide past one another at a relative velocity of 1 cm/sec. Most liquids have viscosities that are only a small fraction of a poise, so that viscosity coefficients ...
... cause two parallel planes of 1 cm2 area 1 cm apart in the liquid to slide past one another at a relative velocity of 1 cm/sec. Most liquids have viscosities that are only a small fraction of a poise, so that viscosity coefficients ...
Page 47
A mixture of gases containing 24.0 g of C0,, 15.5 g of N2, and 100 g of02 is placed in a container of 50 liters volume at a temperature of 23°C. Calculate the mole fraction, partial volume, and partial pressure of each of the three ...
A mixture of gases containing 24.0 g of C0,, 15.5 g of N2, and 100 g of02 is placed in a container of 50 liters volume at a temperature of 23°C. Calculate the mole fraction, partial volume, and partial pressure of each of the three ...
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Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero