Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
From inside the book
Results 1-5 of 65
Page viii
... 152 5-1 Strong and Weak Electrolytes 152 5-2 The Debye—Hiickel Theory; Activity Coefficients of Ions 155 5-3 Conductance 165 54 Enthalpies of Solution and of Reaction of Ions 173 5-5 Ionic Hydration and the Lyotropic Series 176 ...
... 152 5-1 Strong and Weak Electrolytes 152 5-2 The Debye—Hiickel Theory; Activity Coefficients of Ions 155 5-3 Conductance 165 54 Enthalpies of Solution and of Reaction of Ions 173 5-5 Ionic Hydration and the Lyotropic Series 176 ...
Page ix
6—5 6-6 6—7 Characterization of Acid—Base Functional Groups 194 Amino Acids and Proteins 201 Ionic Equilibria in the Blood 208 7/ OXIDATION—REDUCTION EQ 7-1 7-2 7-3 7-4 7-5 7-6 7-7 UILIBRIA Reaction Potentials for Oxidation-Reduction ...
6—5 6-6 6—7 Characterization of Acid—Base Functional Groups 194 Amino Acids and Proteins 201 Ionic Equilibria in the Blood 208 7/ OXIDATION—REDUCTION EQ 7-1 7-2 7-3 7-4 7-5 7-6 7-7 UILIBRIA Reaction Potentials for Oxidation-Reduction ...
Page 26
We now turn to a consideration of the attractive forces associated with the existence of permanent or induced dipoles. Although our present concern is not primarily directed to ionic solutions in such solvents ...
We now turn to a consideration of the attractive forces associated with the existence of permanent or induced dipoles. Although our present concern is not primarily directed to ionic solutions in such solvents ...
Page 47
In general, nonpolar solutes tend to increase the amount of order of water and are termed structure formers, but ionic materials reduce the amount of order and are termed structure breakers. We shall return to the discussion of aqueous ...
In general, nonpolar solutes tend to increase the amount of order of water and are termed structure formers, but ionic materials reduce the amount of order and are termed structure breakers. We shall return to the discussion of aqueous ...
Page 71
For example, iodine can be extracted from aqueous solution by carbon tetrachloride, in which it is highly soluble; the iodine is removed from other solutes—in particular, polar or ionic materials—which may be in the water and at the ...
For example, iodine can be extracted from aqueous solution by carbon tetrachloride, in which it is highly soluble; the iodine is removed from other solutes—in particular, polar or ionic materials—which may be in the water and at the ...
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Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero