Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
From inside the book
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Page 1
This picture is embodied in the kinetic theory, which describes the molecules of a
gas as separated particles in continuous motion. Each molecule travels in a
straight line until it collides with another molecule or strikes the wall of the vessel
in ...
This picture is embodied in the kinetic theory, which describes the molecules of a
gas as separated particles in continuous motion. Each molecule travels in a
straight line until it collides with another molecule or strikes the wall of the vessel
in ...
Page 11
Then - 79.0 cm H z E I (76.0 cm/atm RT [(82.06 cm3 atm/(mol K)](306.0 K) I 9.40 X
10—4 mol )(22.7 cm“) KINETIC THEORY AND DERIVATION OF THE GAS
EQUATION The equation of state, or equation relating P, V, and T for a sample of
gas, ...
Then - 79.0 cm H z E I (76.0 cm/atm RT [(82.06 cm3 atm/(mol K)](306.0 K) I 9.40 X
10—4 mol )(22.7 cm“) KINETIC THEORY AND DERIVATION OF THE GAS
EQUATION The equation of state, or equation relating P, V, and T for a sample of
gas, ...
Page 49
Contains a good section on the kinetic theory of gases. G. C. Pimental and A. L.
McClellan, The Hydrogen Bond, Freeman, San Francisco, 1960. A
comprehensive but readable account, including both the characteristics of
hydrogen bonds and ...
Contains a good section on the kinetic theory of gases. G. C. Pimental and A. L.
McClellan, The Hydrogen Bond, Freeman, San Francisco, 1960. A
comprehensive but readable account, including both the characteristics of
hydrogen bonds and ...
Page 89
ENERGY,. 3-1. WORK,. AND. HEAT. When a force acts upon a material body and
accelerates the body—it may act upon a stationary body and set it in motion, for
example— work is done upon the body and kinetic energy is imparted to it.
ENERGY,. 3-1. WORK,. AND. HEAT. When a force acts upon a material body and
accelerates the body—it may act upon a stationary body and set it in motion, for
example— work is done upon the body and kinetic energy is imparted to it.
Page 90
Kinetic energy is possessed by a body moving through space, which is able to do
work as its velocity is decreased, as by ... and this work becomes the kinetic
energy of its downward motion, which can be reconverted into work when the
falling ...
Kinetic energy is possessed by a body moving through space, which is able to do
work as its velocity is decreased, as by ... and this work becomes the kinetic
energy of its downward motion, which can be reconverted into work when the
falling ...
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Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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Common terms and phrases
absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero