Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Page x
... Diffraction and Polymers 440 12—3 Conformation of Macromolecules in Solution 445 12-4 Filtration and Particle Size 448 12—5 Osmotic Pressure 449 12—6 Dynamic Properties 453 12-7 Sedimentation Equilibrium 463 12-8 Electrophoresis 465 ...
... Diffraction and Polymers 440 12—3 Conformation of Macromolecules in Solution 445 12-4 Filtration and Particle Size 448 12—5 Osmotic Pressure 449 12—6 Dynamic Properties 453 12-7 Sedimentation Equilibrium 463 12-8 Electrophoresis 465 ...
Page 1
This picture is embodied in the kinetic theory, which describes the molecules of a gas as separated particles in continuous motion. Each molecule travels in a straight line until it collides with another molecule or strikes the wall of ...
This picture is embodied in the kinetic theory, which describes the molecules of a gas as separated particles in continuous motion. Each molecule travels in a straight line until it collides with another molecule or strikes the wall of ...
Page 3
A.sing1e phase may be entirely gaseous, or may comprise a single liquid layer, or may be a solid in which all the particles are in the same structural pattern or allotropic form. For liquid water with pieces of ice floating on the ...
A.sing1e phase may be entirely gaseous, or may comprise a single liquid layer, or may be a solid in which all the particles are in the same structural pattern or allotropic form. For liquid water with pieces of ice floating on the ...
Page 24
Although they may be between electrically neutral particles, physical or van der Waals forces are essentially electrical in origin. Despite the fact that an atom or molecule when viewed from a distance is electrically neutral, ...
Although they may be between electrically neutral particles, physical or van der Waals forces are essentially electrical in origin. Despite the fact that an atom or molecule when viewed from a distance is electrically neutral, ...
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When a force of attraction or repulsion exists between two particles, there is necessarily a change in energy when the distance between the particles is altered. For example, if two particles bearing opposite electric charges are ...
When a force of attraction or repulsion exists between two particles, there is necessarily a change in energy when the distance between the particles is altered. For example, if two particles bearing opposite electric charges are ...
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Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero