Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Page 2
... rotation of parts of the molecule or of the entire molecule Figure 1-1 Molecular arrangements typical of (a) a crystalline solid, (b) a liquid or amorphous solid, and (c) a gas. %. gaeéi'gi'égéigé. segegeeeesg. OO GOO OOOOOQOCSDOOCOCO C. a.
... rotation of parts of the molecule or of the entire molecule Figure 1-1 Molecular arrangements typical of (a) a crystalline solid, (b) a liquid or amorphous solid, and (c) a gas. %. gaeéi'gi'égéigé. segegeeeesg. OO GOO OOOOOQOCSDOOCOCO C. a.
Page 27
... rotating or diffusing molecule, its average energy of interaction with an ion is not dependent upon temperature. The magnitude of the induced dipole depends upon the ease with which the electron cloud of'a molecule responds to the ...
... rotating or diffusing molecule, its average energy of interaction with an ion is not dependent upon temperature. The magnitude of the induced dipole depends upon the ease with which the electron cloud of'a molecule responds to the ...
Page 99
... rotations. Each of these rotations is about one of two axes which are perpendicular to one another and to the axis of the molecule, and which pass through the center of mass of the molecule. For such linear molecules, rotation about the ...
... rotations. Each of these rotations is about one of two axes which are perpendicular to one another and to the axis of the molecule, and which pass through the center of mass of the molecule. For such linear molecules, rotation about the ...
Page 100
... rotate about any or all of three mutually perpendicular axes, these axes, too, passing through the center of mass of the molecule. Once more each mode of rotation contributes about %R to the molar heat capacity, following the ...
... rotate about any or all of three mutually perpendicular axes, these axes, too, passing through the center of mass of the molecule. Once more each mode of rotation contributes about %R to the molar heat capacity, following the ...
Page 101
... rotation by specifying the orientation in space of the molecular axis with respect to some frame of reference. For a nonlinear molecule, three coordinates are associated with rotation. The remainder of the coordinates, 3N — 5 or 3N — 6 ...
... rotation by specifying the orientation in space of the molecular axis with respect to some frame of reference. For a nonlinear molecule, three coordinates are associated with rotation. The remainder of the coordinates, 3N — 5 or 3N — 6 ...
Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero