Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Results 1-5 of 59
Page viii
... Entropy and Probability 123 4-7 The Free Energy Function and its Significance 128 4-8 Chemical Equilibrium 134 4-9 Effect of Temperature on Free Energy Change and Equilibrium Constant 137 4-10 Energy Relations in Living Systems 139 ...
... Entropy and Probability 123 4-7 The Free Energy Function and its Significance 128 4-8 Chemical Equilibrium 134 4-9 Effect of Temperature on Free Energy Change and Equilibrium Constant 137 4-10 Energy Relations in Living Systems 139 ...
Page 5
... further their significance in Section 1-7. The phase diagram for the substance carbon dioxide is shown in Figure 1-3. In some respects, it resembles the diagram for water, but the triple point is at a pressure exceeding 1 atm, ...
... further their significance in Section 1-7. The phase diagram for the substance carbon dioxide is shown in Figure 1-3. In some respects, it resembles the diagram for water, but the triple point is at a pressure exceeding 1 atm, ...
Page 8
... have a significance wider than mere application in the calculation of gaseous volumes. DIMENSIONAL NATURE OF THE GAS EQUATION Let us now analyze the dimensional characteristics of the ideal gas equation.
... have a significance wider than mere application in the calculation of gaseous volumes. DIMENSIONAL NATURE OF THE GAS EQUATION Let us now analyze the dimensional characteristics of the ideal gas equation.
Page 9
... it is sufficient to use for R values rounded to three significant figures, 82.1 cm3 atm/(mol K) or 0.0821 liter atm/(mol K.) Since R represents a quantity of energy per mole per degree, it is often desirable to use a numerical value ...
... it is sufficient to use for R values rounded to three significant figures, 82.1 cm3 atm/(mol K) or 0.0821 liter atm/(mol K.) Since R represents a quantity of energy per mole per degree, it is often desirable to use a numerical value ...
Page 17
The partial pressure of a gas in a mixture is significant as an indication of the concentration of the substance to which it refers; for most purposes the concentration governs the behavior of a gaseous substance regardless of the ...
The partial pressure of a gas in a mixture is significant as an indication of the concentration of the substance to which it refers; for most purposes the concentration governs the behavior of a gaseous substance regardless of the ...
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Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero