Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Page 5
Only under the conditions represented by this point, a temperature of 0.0100°C
and a pressure of 4.579 torr, is it possible for all three phases, solid, liquid, and
gas, to be together in equilibrium. If the three phases are mixed together at any ...
Only under the conditions represented by this point, a temperature of 0.0100°C
and a pressure of 4.579 torr, is it possible for all three phases, solid, liquid, and
gas, to be together in equilibrium. If the three phases are mixed together at any ...
Page 69
In Table 2-3 are listed upper and lower critical solution temperatures for a few
representative liquid pairs. Some partially miscible liquid pairs show increasing
solubility as the temperature is raised but, at least at atmospheric pressure, never
...
In Table 2-3 are listed upper and lower critical solution temperatures for a few
representative liquid pairs. Some partially miscible liquid pairs show increasing
solubility as the temperature is raised but, at least at atmospheric pressure, never
...
Page 89
Heat is the term applied to energy transferred from one place to another because
of a temperature difference between the two locations. When heat is taken up by
a sample of material, the effect is ob— served as a rise in the temperature of ...
Heat is the term applied to energy transferred from one place to another because
of a temperature difference between the two locations. When heat is taken up by
a sample of material, the effect is ob— served as a rise in the temperature of ...
Page 108
3-6 increase in each of the reactants or products can be calculated by simply
multiplying its heat capacity at constant pressure by the relevant temperature
interval. Consequently, the enthalpy change for the process at temperature T2 is
related ...
3-6 increase in each of the reactants or products can be calculated by simply
multiplying its heat capacity at constant pressure by the relevant temperature
interval. Consequently, the enthalpy change for the process at temperature T2 is
related ...
Page 109
dures, it is appropriate to describe some of the methods of measuring
temperature that can be employed. The most familiar type of thermometer
employs the expansion of a liquid as an indication of Change in temperature. The
accuracy is ...
dures, it is appropriate to describe some of the methods of measuring
temperature that can be employed. The most familiar type of thermometer
employs the expansion of a liquid as an indication of Change in temperature. The
accuracy is ...
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Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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Common terms and phrases
absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero