Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Results 1-5 of 71
Page ix
... Ions 303 Vibrations in Diatomic Molecules 306 An Overview of Molecular Spectroscopy 311 Vibrational Spectra 313 Electronic Transitions 322 Optical Dispersion 329 213 244 288 10 / KINETICS OF CHEMICAL REACTIONS 338 10-1 Rates and.
... Ions 303 Vibrations in Diatomic Molecules 306 An Overview of Molecular Spectroscopy 311 Vibrational Spectra 313 Electronic Transitions 322 Optical Dispersion 329 213 244 288 10 / KINETICS OF CHEMICAL REACTIONS 338 10-1 Rates and.
Page x
... Equation 357 10-7 Transition-State Theory 359 10-8 Catalysis 369 10-9 Enzyme-Catalyzed Reactions 378 10-10 Isotope Effects 389 10-11 Very Rapid Reactions 391 11/ADSORPTION AND SURFACE EFFECTS 403 11-1 Energy Relations and Adsorption ...
... Equation 357 10-7 Transition-State Theory 359 10-8 Catalysis 369 10-9 Enzyme-Catalyzed Reactions 378 10-10 Isotope Effects 389 10-11 Very Rapid Reactions 391 11/ADSORPTION AND SURFACE EFFECTS 403 11-1 Energy Relations and Adsorption ...
Page 23
... to be expected if the substance obeys the van der Waals equation in the transition to the liquid state. When the van der Waals equation is multiplied out and arranged in descending powers of the molar volume, it becomes RT 0 ab_ ...
... to be expected if the substance obeys the van der Waals equation in the transition to the liquid state. When the van der Waals equation is multiplied out and arranged in descending powers of the molar volume, it becomes RT 0 ab_ ...
Page 77
We turn now to the other colligative property involving the temperature of a phase transition, elevation of the boiling point. The lowering of the vapor pressure of the solvent by the solute requires that a solution be raised to a ...
We turn now to the other colligative property involving the temperature of a phase transition, elevation of the boiling point. The lowering of the vapor pressure of the solvent by the solute requires that a solution be raised to a ...
Page 111
Types of processes that have been studied by these methods include conformational transitions of macromolecules, the coupling of substrate to enzyme, the progress of ...
Types of processes that have been studied by these methods include conformational transitions of macromolecules, the coupling of substrate to enzyme, the progress of ...
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Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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Common terms and phrases
absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero