Physical Chemistry and Its Biological ApplicationsPhysical Chemistry and Its Biological Applications presents the basic principles of physical chemistry and shows how the methods of physical chemistry are being applied to increase understanding of living systems. Chapters 1 and 2 of the book discuss states of matter and solutions of nonelectrolytes. Chapters 3 to 5 examine laws in thermodynamics and solutions of electrolytes. Chapters 6 to 8 look at acid-base equilibria and the link between electromagnetic radiation and the structure of atoms. Chapters 9 to 11 cover different types of bonding, the rates of chemical reactions, and the process of adsorption. Chapters 12 to 14 present molecular aggregates, magnetic resonance spectroscopy and photochemistry, and radiation. This book is useful to biological scientists for self-study and reference. With modest additions of mathematical material by the teacher, the book should also be suitable for a full-year major's course in physical chemistry. |
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Page vii
... Measurement of Gases 16 Real Gases 19 Continuity of States; Corresponding States 21 Intermolecular Forces 24 The Hydrogen Bond 30 Vapor Pressure 32 Surface Tension 37 Viscosity 41 Structure of Liquids 44 2/ SOLUTIONS OF ...
... Measurement of Gases 16 Real Gases 19 Continuity of States; Corresponding States 21 Intermolecular Forces 24 The Hydrogen Bond 30 Vapor Pressure 32 Surface Tension 37 Viscosity 41 Structure of Liquids 44 2/ SOLUTIONS OF ...
Page 3
A sample of water may be in the vapor phase, in the liquid phase, in the solid phase which is commonly encountered as ice, or in one of a variety of other solid phases which appear at high pressures and which differ from ordinary ice by ...
A sample of water may be in the vapor phase, in the liquid phase, in the solid phase which is commonly encountered as ice, or in one of a variety of other solid phases which appear at high pressures and which differ from ordinary ice by ...
Page 4
Thus there is only one pressure under which the liquid and vapor of a pure substance can coexist permanently at a given temperature. Similar considerations apply to the vapor and solid: At —10°C, for example, vapor can exist by itself ...
Thus there is only one pressure under which the liquid and vapor of a pure substance can coexist permanently at a given temperature. Similar considerations apply to the vapor and solid: At —10°C, for example, vapor can exist by itself ...
Page 5
Only under the conditions represented by this point, a temperature of 0.0100°C and a pressure of 4.579 torr, is it possible for all three phases, ... Under these conditions, most of the pressure of the vapor phase is contributed by air.
Only under the conditions represented by this point, a temperature of 0.0100°C and a pressure of 4.579 torr, is it possible for all three phases, ... Under these conditions, most of the pressure of the vapor phase is contributed by air.
Page 10
Example: A sample of 0.250 g of a pure liquid is vaporized, and the vapor is collected in a buret over mercury as the confining liquid. The gas in the buret is at a pressure of 745 torr and a temperature of 600°C. Calculate the ...
Example: A sample of 0.250 g of a pure liquid is vaporized, and the vapor is collected in a buret over mercury as the confining liquid. The gas in the buret is at a pressure of 745 torr and a temperature of 600°C. Calculate the ...
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Contents
1 | |
51 | |
89 | |
SECOND LAW AND EQUILIBRIUM | 115 |
CHAPTER 5 SOLUTIONS OF ELECTROLYTES | 152 |
CHAPTER 6 ACIDBASE EQUILIBRIA | 181 |
CHAPTER 7 OXIDATIONREDUCTION EQUILIBRIA | 213 |
CHAPTER 8 ELECTROMAGNETIC RADIATION AND THE STRUCTURE OF ATOMS | 244 |
CHAPTER 10 KINETICS OF CHEMICAL REACTIONS | 338 |
CHAPTER 11 ADSORPTION AND SURFACE EFFECTS | 403 |
CHAPTER 12 MACROMOLECULES AND MOLECULAR AGGREGATES | 436 |
CHAPTER 13 MAGNETIC RESONANCE SPECTROSCOPY | 494 |
CHAPTER 14 PHOTOCHEMISTRY AND RADIATION CHEMISTRY | 536 |
Table of Symbols and Abbreviations | 581 |
Index | 583 |
CHAPTER 9 BONDING AND MOLECULAR SPECTROSCOPY | 288 |
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absorption acid activity adsorbed adsorption amino amount applied benzene bond Calculate carbon carboxyl cell chain charge Chem chemical chemical shift chloride coefficient colligative properties complex components concentration corresponding curve defined described diagram dissociation effect electric electrolyte electron energy change enthalpy entropy enzyme equal equation equilibrium constant example film first flow force fraction free energy frequency function heat hydrogen atom hydrogen ion increase ionic ionization kcal kinetic liquid magnetic field material measured membrane mixture molar mole mole fraction molecules nucleus occurs orbital osmotic pressure oxidation oxygen particles phase polar potential protein proton quantum number radiation rate constant ratio reactant reaction resonance rotation sample shown in Figure significant sodium solid solubility solvent species specific spectra spectrum spin structure substrate sucrose surface tension temperature tion titration transition triplet vapor pressure velocity vibrational volume wave wavelength zero