Solid State Behavior of Linear Polyesters and Polyamides |
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Page 299
... FCP rates in the fully or more amorphous skin and in the crystalline core were first distinguished for the example of PA - 6 ( Figure 32 ) [ 25 ] . It clearly shows that the FCP resistance of the more amorphous skin layer is lower than ...
... FCP rates in the fully or more amorphous skin and in the crystalline core were first distinguished for the example of PA - 6 ( Figure 32 ) [ 25 ] . It clearly shows that the FCP resistance of the more amorphous skin layer is lower than ...
Page 313
... FCP rate with microstructural efficiency factor , M , schematically . The region where the PARIS power law is valid is designed by solid line . lar structure ( spherulites , row structures ) , and flow - induced topology ( skin- core ...
... FCP rate with microstructural efficiency factor , M , schematically . The region where the PARIS power law is valid is designed by solid line . lar structure ( spherulites , row structures ) , and flow - induced topology ( skin- core ...
Contents
SOLID STATE REACTIONS IN LINEAR | 1 |
CHEMICAL HEALING | 43 |
PRACTICAL ASPECTS OF ADDITIONAL SOLID STATE | 59 |
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acid additional solid amorphous annealing Appl aspect ratio behavior birefringence block temperature chain Chem composites copolyester copolymer courtesy crystallinity crystallization curves decreases deformation degree of crystallinity density diameter diffusion domains Dröscher effect Equation exchange reactions extrusion temperature Fakirov fiber axis fibers drawn filament fracture mechanics fracture toughness function heat of fusion heated element higher increasing initial kg/cm² kinetics linear polycondensates load macromolecules Makromol material matrix maximum measurements mechanical melting point microfibrils microstructure mm/min modulus molded molecules morphology nominal draw ratio noncrystalline nylon 6 fibers nylon 66 orientation parameters peak PET fibers phase Phys polyamides polyesters Polymer Sci polymerization properties Reprinted from Ref samples SAXS Schultz semicrystalline shown in Figure solid state polycondensation solid state post-polycondensation solid state reactions Solid-state extrusion specimen spherulite strength stress structure Table tensile terephthalate thermoplastics toughened transesterification transreactions values x-ray yield Zachmann