Solid State Behavior of Linear Polyesters and Polyamides |
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Page 299
Skin - Core Morphology FCP rates in the fully or more amorphous skin and in the
crystalline core were first distinguished for the example of PA - 6 ( Figure 32 ) ( 25
) . It clearly shows that the FCP resistance of the more amorphous skin layer is ...
Skin - Core Morphology FCP rates in the fully or more amorphous skin and in the
crystalline core were first distinguished for the example of PA - 6 ( Figure 32 ) ( 25
) . It clearly shows that the FCP resistance of the more amorphous skin layer is ...
Page 313
11 Paris law not valid MP 6017 n o AK = const . no Matrix → Composites = log M
Figure 42 . Variation of FCP rate with microstructural efficiency factor , M ,
schematically . The region where the PARIS power law is valid is designed by
solid line ...
11 Paris law not valid MP 6017 n o AK = const . no Matrix → Composites = log M
Figure 42 . Variation of FCP rate with microstructural efficiency factor , M ,
schematically . The region where the PARIS power law is valid is designed by
solid line ...
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achieved acid additional amorphous annealing Appl applied aspect average behavior block bonding changes Chem chemical composites conclusion constant crack crystallinity crystallization curves decreases deformation density depends determined diameter diffusion direction distribution domains draw ratio drawn effect element energy Equation experiments extrusion factor fatigue fiber Figure fracture fracture toughness function given groups growth healing heat higher important increasing indicated initial length linear load lower material matrix maximum measurements mechanical melt method microfibrils microstructure modulus molded molecular weight molecules nylon nylon 66 observed obtained occurs orientation peak phase Phys polyamides polycondensation polyesters Polymer Sci polymerization properties range reaction regions reported Reprinted from Ref respectively samples SAXS scattering shows solid solid state polycondensation solid-state specimen speed stage strain strength stress structure studied Table temperature tensile units values yield