Solid state behavior of linear polyesters and polyamides |
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Page 152
With this model, then, the modulus of the fiber is determined solely by the
modulus of the microfibril, which in turn is determined by the combination of the
moduli of the alternating amorphous and crystalline regions when they are
loaded under ...
With this model, then, the modulus of the fiber is determined solely by the
modulus of the microfibril, which in turn is determined by the combination of the
moduli of the alternating amorphous and crystalline regions when they are
loaded under ...
Page 172
Factors Affecting the Shift of Amorphous, Unoriented Tg to that in Crystalline
Oriented Samples Amorphous orientation (Integral breadth in degrees of the Size
of Degree of azimuthal intensity Long amorphous crystallinity, % distribution)
period ...
Factors Affecting the Shift of Amorphous, Unoriented Tg to that in Crystalline
Oriented Samples Amorphous orientation (Integral breadth in degrees of the Size
of Degree of azimuthal intensity Long amorphous crystallinity, % distribution)
period ...
Page 173
of crystalline (£c) and amorphous (£a) domains (Figure 23). mil i=ec+ea Figure
23. Schematic representation of crystalline lamellae (length £e) and interlamellar
amorphous region (length c0). I is the long period from SAXS measurements.
of crystalline (£c) and amorphous (£a) domains (Figure 23). mil i=ec+ea Figure
23. Schematic representation of crystalline lamellae (length £e) and interlamellar
amorphous region (length c0). I is the long period from SAXS measurements.
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Contents
SUMMARY | 1 |
TRANSREACTIONS AND POSTADDITIONAL | 19 |
CHEMICAL HEALING | 43 |
Copyright | |
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Common terms and phrases
acid additional solid amorphous annealing Appl aspect ratio behavior birefringence block temperature chain Chem composites condensation copolyester copolymer courtesy crystallinity crystallization curves decrease deformation degree of crystallinity density diameter diffusion domains draw ratio Droscher effect Equation exchange reactions extrusion temperature Fakirov fiber axis fibers drawn filament fracture mechanics fracture toughness function heated element higher increase initial kinetics linear polycondensates load macromolecules Makromol material matrix maximum measurements mechanical melting point microfibrils microstructure modulus molded molecules morphology Nelon nominal draw ratio noncrystalline nylon 6 fibers nylon 66 obtained orientation parameters peak PET fibers phase Phys Plastic poly polyamides polyesters Polymer Sci polymerization properties Reprinted from Ref samples SAXS Schultz semicrystalline shown in Figure solid state polycondensation solid state post-polycondensation solid state reactions Solid-state extrusion specimen spherulite spinning strength stress structure Table tensile terephthalate thermoplastics toughened transesterification transreactions values x-ray yield Zachmann
Bibliographic information
| Title | Solid state behavior of linear polyesters and polyamides Prentice Hall international series in the physical and chemical engineering sciences Prentice Hall International Series in the Physical and Chemi |
| Authors | Jerold M. Schultz, Stoĭko Fakirov |
| Editors | Jerold M. Schultz, Stoĭko Fakirov |
| Contributor | Jerold M. Schultz |
| Edition | illustrated |
| Publisher | Prentice Hall, 1990 |
| Original from | the University of Michigan |
| Digitized | 15 Dec 2007 |
| ISBN | 0138247315, 9780138247317 |
| Length | 325 pages |
| Subjects | › › Polyesters Polyimides Science / Chemistry / Inorganic Technology & Engineering / Chemical & Biochemical Technology & Engineering / Material Science Technology & Engineering / Textiles & Polymers |
| Export Citation | BiBTeX EndNote RefMan |