Solid State Behavior of Linear Polyesters and Polyamides |
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Page 90
... crystalline reflections from the level expected for a 100 % crystalline mass of perfect crystals . Ruland pointed out that , while this is so , the effect of crystallinity of degree X is to reduce all peaks by the same relative amount ...
... crystalline reflections from the level expected for a 100 % crystalline mass of perfect crystals . Ruland pointed out that , while this is so , the effect of crystallinity of degree X is to reduce all peaks by the same relative amount ...
Page 120
... crystalline state predicted by Tiller and Schultz [ 116 ] . PHASE INDEX 100 Am 40 -0- 201 Cr . Crystalline Index Mesophase Index Mesophase Index Amorphous Phase Crystalline Phase Meso Oriented Mesophase D.A. 1 2 3 4 5 6 7 8 9 TAKE - UP ...
... crystalline state predicted by Tiller and Schultz [ 116 ] . PHASE INDEX 100 Am 40 -0- 201 Cr . Crystalline Index Mesophase Index Mesophase Index Amorphous Phase Crystalline Phase Meso Oriented Mesophase D.A. 1 2 3 4 5 6 7 8 9 TAKE - UP ...
Page 173
... crystalline domains in the microfibrils . Figure 24 shows the SAXS merid- ional scans of the two fibers . Since the reflection of nylon 66 is much wider than that of nylon 6 , the variations in crystalline and amorphous domain length ...
... crystalline domains in the microfibrils . Figure 24 shows the SAXS merid- ional scans of the two fibers . Since the reflection of nylon 66 is much wider than that of nylon 6 , the variations in crystalline and amorphous domain length ...
Contents
SOLID STATE REACTIONS IN LINEAR | 1 |
CHEMICAL HEALING | 43 |
PRACTICAL ASPECTS OF ADDITIONAL SOLID STATE | 59 |
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acid additional solid amorphous annealing Appl aspect ratio behavior birefringence block temperature chain Chem composites copolyester copolymer courtesy crystallinity crystallization curves decreases deformation degree of crystallinity density diameter diffusion domains Dröscher effect Equation exchange reactions extrusion temperature Fakirov fiber axis fibers drawn filament fracture mechanics fracture toughness function heat of fusion heated element higher increasing initial kg/cm² kinetics linear polycondensates load macromolecules Makromol material matrix maximum measurements mechanical melting point microfibrils microstructure mm/min modulus molded molecules morphology nominal draw ratio noncrystalline nylon 6 fibers nylon 66 orientation parameters peak PET fibers phase Phys polyamides polyesters Polymer Sci polymerization properties Reprinted from Ref samples SAXS Schultz semicrystalline shown in Figure solid state polycondensation solid state post-polycondensation solid state reactions Solid-state extrusion specimen spherulite strength stress structure Table tensile terephthalate thermoplastics toughened transesterification transreactions values x-ray yield Zachmann