Solid State Behavior of Linear Polyesters and Polyamides |
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Page 11
... distribution . For example , two average molecules may react to produce a much longer and a much shorter molecule . Conversely , if a mixture consists of two species , one very long , they may possibly interchange with each other to ...
... distribution . For example , two average molecules may react to produce a much longer and a much shorter molecule . Conversely , if a mixture consists of two species , one very long , they may possibly interchange with each other to ...
Page 31
... distribution is another important aspect of solid state post - polycondensation . The nature of molec- ular weight distribution in linear chain molecules was studied in detail by Flory [ 12 ] . The theoretically derived molecular size ...
... distribution is another important aspect of solid state post - polycondensation . The nature of molec- ular weight distribution in linear chain molecules was studied in detail by Flory [ 12 ] . The theoretically derived molecular size ...
Page 33
... distribution may easily be explained by the non - observance of the basic assumption in his consideration , namely , achievement of equilibrium in the polycondensation process . Incidentally , the equilibrium of the solid state ...
... distribution may easily be explained by the non - observance of the basic assumption in his consideration , namely , achievement of equilibrium in the polycondensation process . Incidentally , the equilibrium of the solid state ...
Contents
SOLID STATE REACTIONS IN LINEAR | 1 |
CHEMICAL HEALING | 43 |
PRACTICAL ASPECTS OF ADDITIONAL SOLID STATE | 59 |
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acid additional solid amorphous annealing Appl aspect ratio behavior birefringence block temperature chain Chem composites copolyester copolymer courtesy crystallinity crystallization curves decreases deformation degree of crystallinity density diameter diffusion domains Dröscher effect Equation exchange reactions extrusion temperature Fakirov fiber axis fibers drawn filament fracture mechanics fracture toughness function heat of fusion heated element higher increasing initial kg/cm² kinetics linear polycondensates load macromolecules Makromol material matrix maximum measurements mechanical melting point microfibrils microstructure mm/min modulus molded molecules morphology nominal draw ratio noncrystalline nylon 6 fibers nylon 66 orientation parameters peak PET fibers phase Phys polyamides polyesters Polymer Sci polymerization properties Reprinted from Ref samples SAXS Schultz semicrystalline shown in Figure solid state polycondensation solid state post-polycondensation solid state reactions Solid-state extrusion specimen spherulite strength stress structure Table tensile terephthalate thermoplastics toughened transesterification transreactions values x-ray yield Zachmann