Solid State Behavior of Linear Polyesters and Polyamides |
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Page 136
Peterlin proposes that the PE fiber , strength should be attributed primarily to the
strength of the microfibrils , with the interfibrillar domains contributing much less [
1 ] . With nylon and PET fibers , on the other hand , the situation is quite different ...
Peterlin proposes that the PE fiber , strength should be attributed primarily to the
strength of the microfibrils , with the interfibrillar domains contributing much less [
1 ] . With nylon and PET fibers , on the other hand , the situation is quite different ...
Page 158
Thus , the order of these domains is higher than that of the amorphous domains
in the microfibril and lower than that of the crystallites of the microfibril . Because
the inter - fibrillar domain consists predominantly of extended - chain molecules ...
Thus , the order of these domains is higher than that of the amorphous domains
in the microfibril and lower than that of the crystallites of the microfibril . Because
the inter - fibrillar domain consists predominantly of extended - chain molecules ...
Page 172
Since the amorphous domain in nylon 6 is shorter than in nylon 66 , the
amorphous molecules are under more severe ... and the size of the amorphous
domains ( by vertical and horizontal shifting of the two dispersion leaks ) , the loss
peak of ...
Since the amorphous domain in nylon 6 is shorter than in nylon 66 , the
amorphous molecules are under more severe ... and the size of the amorphous
domains ( by vertical and horizontal shifting of the two dispersion leaks ) , the loss
peak of ...
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achieved acid additional amorphous annealing Appl applied aspect average behavior block bonding changes Chem chemical composites conclusion constant crack crystallinity crystallization curves decreases deformation density depends determined diameter diffusion direction distribution domains draw ratio drawn effect element energy Equation experiments extrusion factor fatigue fiber Figure fracture fracture toughness function given groups growth healing heat higher important increasing indicated initial length linear load lower material matrix maximum measurements mechanical melt method microfibrils microstructure modulus molded molecular weight molecules nylon nylon 66 observed obtained occurs orientation peak phase Phys polyamides polycondensation polyesters Polymer Sci polymerization properties range reaction regions reported Reprinted from Ref respectively samples SAXS scattering shows solid solid state polycondensation solid-state specimen speed stage strain strength stress structure studied Table temperature tensile units values yield