Solid State Behavior of Linear Polyesters and Polyamides |
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Page 136
... domains contributing much less [ 1 ] . With nylon and PET fibers , on the other hand , the situation is quite different : The extended - chain inter - fibrillar domains are the strongest el- ement of fiber structure , and have an ...
... domains contributing much less [ 1 ] . With nylon and PET fibers , on the other hand , the situation is quite different : The extended - chain inter - fibrillar domains are the strongest el- ement of fiber structure , and have an ...
Page 158
... domains is higher than that of the amorphous domains in the microfibril and lower than that of the crystallites of the microfibril . Be- cause the inter - fibrillar domain consists predominantly of extended - chain molecules , it ...
... domains is higher than that of the amorphous domains in the microfibril and lower than that of the crystallites of the microfibril . Be- cause the inter - fibrillar domain consists predominantly of extended - chain molecules , it ...
Page 172
... domains . Regardless of the cause , it is clear that the amorphous domains in nylon 6 are much more uniform than in nylon 66 . This rather radical finding requires an independent determination of the distribution of the structure of ...
... domains . Regardless of the cause , it is clear that the amorphous domains in nylon 6 are much more uniform than in nylon 66 . This rather radical finding requires an independent determination of the distribution of the structure of ...
Contents
SOLID STATE REACTIONS IN LINEAR | 1 |
CHEMICAL HEALING | 43 |
PRACTICAL ASPECTS OF ADDITIONAL SOLID STATE | 59 |
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acid additional solid amorphous annealing Appl aspect ratio behavior birefringence block temperature chain Chem composites copolyester copolymer courtesy crystallinity crystallization curves decreases deformation degree of crystallinity density diameter diffusion domains Dröscher effect Equation exchange reactions extrusion temperature Fakirov fiber axis fibers drawn filament fracture mechanics fracture toughness function heat of fusion heated element higher increasing initial kg/cm² kinetics linear polycondensates load macromolecules Makromol material matrix maximum measurements mechanical melting point microfibrils microstructure mm/min modulus molded molecules morphology nominal draw ratio noncrystalline nylon 6 fibers nylon 66 orientation parameters peak PET fibers phase Phys polyamides polyesters Polymer Sci polymerization properties Reprinted from Ref samples SAXS Schultz semicrystalline shown in Figure solid state polycondensation solid state post-polycondensation solid state reactions Solid-state extrusion specimen spherulite strength stress structure Table tensile terephthalate thermoplastics toughened transesterification transreactions values x-ray yield Zachmann