Solid State Behavior of Linear Polyesters and Polyamides |
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Page 135
Because of its molecular simplicity and easy experimentability , PE remains the
most investigated fiber , but the conclusions derived from ... There should be no
doubt that inter - and intrafibrillar tie molecules also exist in PET and nylon fibers .
Because of its molecular simplicity and easy experimentability , PE remains the
most investigated fiber , but the conclusions derived from ... There should be no
doubt that inter - and intrafibrillar tie molecules also exist in PET and nylon fibers .
Page 149
In a drawing process where ( 1 ) the stretching of the microfibrils equals the
macroscopic stretching of the fiber , and ( 2 ) ... crystallites corresponds
approximately to the width of the microfibril , the crystallite width ratio of fibers
drawn 3 and 5 .
In a drawing process where ( 1 ) the stretching of the microfibrils equals the
macroscopic stretching of the fiber , and ( 2 ) ... crystallites corresponds
approximately to the width of the microfibril , the crystallite width ratio of fibers
drawn 3 and 5 .
Page 203
Figures 41 and 44 show the effect of the first - stage draw ratio on the properties
on the final fiber . In both experiments ( with constant and varying second - stage
block temperature ) , the precursor fibers with the lowest first - stage draw ratio ( 2
...
Figures 41 and 44 show the effect of the first - stage draw ratio on the properties
on the final fiber . In both experiments ( with constant and varying second - stage
block temperature ) , the precursor fibers with the lowest first - stage draw ratio ( 2
...
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achieved acid additional amorphous annealing Appl applied aspect average behavior block bonding changes Chem chemical composites conclusion constant crack crystallinity crystallization curves decreases deformation density depends determined diameter diffusion direction distribution domains draw ratio drawn effect element energy Equation experiments extrusion factor fatigue fiber Figure fracture fracture toughness function given groups growth healing heat higher important increasing indicated initial length linear load lower material matrix maximum measurements mechanical melt method microfibrils microstructure modulus molded molecular weight molecules nylon nylon 66 observed obtained occurs orientation peak phase Phys polyamides polycondensation polyesters Polymer Sci polymerization properties range reaction regions reported Reprinted from Ref respectively samples SAXS scattering shows solid solid state polycondensation solid-state specimen speed stage strain strength stress structure studied Table temperature tensile units values yield