Solid State Behavior of Linear Polyesters and Polyamides |
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Page 55
... heat treatment temperatures corre- spond to higher interface shear stress values may also be interpreted as " more numerous and more stressed contact points increased chemical re- activity . " The higher the temperature ( Th , in this ...
... heat treatment temperatures corre- spond to higher interface shear stress values may also be interpreted as " more numerous and more stressed contact points increased chemical re- activity . " The higher the temperature ( Th , in this ...
Page 103
... heat of fusion and / or noncrystallizable molecules can be transported away from the growth front . The implications of this limitation will be addressed later . 4.2 . Development of Microstructure 4.2.1 . During heat - treatment ...
... heat of fusion and / or noncrystallizable molecules can be transported away from the growth front . The implications of this limitation will be addressed later . 4.2 . Development of Microstructure 4.2.1 . During heat - treatment ...
Page 109
... Heat Flow Melt X ( 1 ) Interface Motion Heat of fusion deposited at the interface ( a ) ( b ) Figure 22. Sketches of ( a ) planar and ( b ) rodlike growth . In ( a ) dif- fusion of heat away from the growth surface is one - dimensional ...
... Heat Flow Melt X ( 1 ) Interface Motion Heat of fusion deposited at the interface ( a ) ( b ) Figure 22. Sketches of ( a ) planar and ( b ) rodlike growth . In ( a ) dif- fusion of heat away from the growth surface is one - dimensional ...
Contents
SOLID STATE REACTIONS IN LINEAR | 1 |
CHEMICAL HEALING | 43 |
PRACTICAL ASPECTS OF ADDITIONAL SOLID STATE | 59 |
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acid additional solid amorphous annealing Appl aspect ratio behavior birefringence block temperature chain Chem composites copolyester copolymer courtesy crystallinity crystallization curves decreases deformation degree of crystallinity density diameter diffusion domains Dröscher effect Equation exchange reactions extrusion temperature Fakirov fiber axis fibers drawn filament fracture mechanics fracture toughness function heat of fusion heated element higher increasing initial kg/cm² kinetics linear polycondensates load macromolecules Makromol material matrix maximum measurements mechanical melting point microfibrils microstructure mm/min modulus molded molecules morphology nominal draw ratio noncrystalline nylon 6 fibers nylon 66 orientation parameters peak PET fibers phase Phys polyamides polyesters Polymer Sci polymerization properties Reprinted from Ref samples SAXS Schultz semicrystalline shown in Figure solid state polycondensation solid state post-polycondensation solid state reactions Solid-state extrusion specimen spherulite strength stress structure Table tensile terephthalate thermoplastics toughened transesterification transreactions values x-ray yield Zachmann