Solid State Behavior of Linear Polyesters and Polyamides |
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Page 18
... involving a carboxyl - terminated macromolecule ( PBT - COOH or PC - COOH ) . The re- action can also involve a direct ester - ester interchange between a PBT and a PC unit . So as to evaluate the contribution of each of these three ...
... involving a carboxyl - terminated macromolecule ( PBT - COOH or PC - COOH ) . The re- action can also involve a direct ester - ester interchange between a PBT and a PC unit . So as to evaluate the contribution of each of these three ...
Page 27
... involves both chemical reaction and diffusion within the material . In a subsequent study , Chen and Griskey [ 101 ] treat this combined chem- ical action and diffusion in a more fundamental manner . They start from the basic ...
... involves both chemical reaction and diffusion within the material . In a subsequent study , Chen and Griskey [ 101 ] treat this combined chem- ical action and diffusion in a more fundamental manner . They start from the basic ...
Page 205
... involves combinations of process variables that are not achievable with conventional scientific experi- ments and ... involve large temperature and deformation gradients . In spite of these differences , this section shows that it is ...
... involves combinations of process variables that are not achievable with conventional scientific experi- ments and ... involve large temperature and deformation gradients . In spite of these differences , this section shows that it is ...
Contents
SOLID STATE REACTIONS IN LINEAR | 1 |
CHEMICAL HEALING | 43 |
PRACTICAL ASPECTS OF ADDITIONAL SOLID STATE | 59 |
Copyright | |
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acid additional solid amorphous annealing Appl aspect ratio behavior birefringence block temperature chain Chem composites copolyester copolymer courtesy crystallinity crystallization curves decreases deformation degree of crystallinity density diameter diffusion domains Dröscher effect Equation exchange reactions extrusion temperature Fakirov fiber axis fibers drawn filament fracture mechanics fracture toughness function heat of fusion heated element higher increasing initial kg/cm² kinetics linear polycondensates load macromolecules Makromol material matrix maximum measurements mechanical melting point microfibrils microstructure mm/min modulus molded molecules morphology nominal draw ratio noncrystalline nylon 6 fibers nylon 66 orientation parameters peak PET fibers phase Phys polyamides polyesters Polymer Sci polymerization properties Reprinted from Ref samples SAXS Schultz semicrystalline shown in Figure solid state polycondensation solid state post-polycondensation solid state reactions Solid-state extrusion specimen spherulite strength stress structure Table tensile terephthalate thermoplastics toughened transesterification transreactions values x-ray yield Zachmann