Solid State Behavior of Linear Polyesters and Polyamides |
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Page 2
... linear polycondensates at high temperatures involve chemical reactions between macromolecules or parts of them ... linear polycondensates , although they have long been known , are as yet insufficiently investigated . They represent an ...
... linear polycondensates at high temperatures involve chemical reactions between macromolecules or parts of them ... linear polycondensates , although they have long been known , are as yet insufficiently investigated . They represent an ...
Page 3
... linear polycondensates " is taken as solely referring to the type of heterochain macromolecules , obtainable either by addition poly- merization or by polycondensation reactions . The polycondensation process relates to the fundamental ...
... linear polycondensates " is taken as solely referring to the type of heterochain macromolecules , obtainable either by addition poly- merization or by polycondensation reactions . The polycondensation process relates to the fundamental ...
Page 66
... polycondensates studied . With respect to the kinetics and mechanism of solid state reactions in linear polycondensates , there is another unsolved problem , namely , how to accelerate these reactions and so to enhance the industrial ...
... polycondensates studied . With respect to the kinetics and mechanism of solid state reactions in linear polycondensates , there is another unsolved problem , namely , how to accelerate these reactions and so to enhance the industrial ...
Contents
SOLID STATE REACTIONS IN LINEAR | 1 |
CHEMICAL HEALING | 43 |
PRACTICAL ASPECTS OF ADDITIONAL SOLID STATE | 59 |
Copyright | |
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acid additional solid amorphous annealing Appl aspect ratio behavior birefringence block temperature chain Chem composites copolyester copolymer courtesy crystallinity crystallization curves decreases deformation degree of crystallinity density diameter diffusion domains Dröscher effect Equation exchange reactions extrusion temperature Fakirov fiber axis fibers drawn filament fracture mechanics fracture toughness function heat of fusion heated element higher increasing initial kg/cm² kinetics linear polycondensates load macromolecules Makromol material matrix maximum measurements mechanical melting point microfibrils microstructure mm/min modulus molded molecules morphology nominal draw ratio noncrystalline nylon 6 fibers nylon 66 orientation parameters peak PET fibers phase Phys polyamides polyesters Polymer Sci polymerization properties Reprinted from Ref samples SAXS Schultz semicrystalline shown in Figure solid state polycondensation solid state post-polycondensation solid state reactions Solid-state extrusion specimen spherulite strength stress structure Table tensile terephthalate thermoplastics toughened transesterification transreactions values x-ray yield Zachmann