Solid State Behavior of Linear Polyesters and Polyamides |
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Page 59
... Mechanical Properties and Processing Behavior Although there are more than 150,000 new polymers synthesized annu- ally in the world's research laboratories [ 185 ] , the number of commercially produced polymers has remained almost ...
... Mechanical Properties and Processing Behavior Although there are more than 150,000 new polymers synthesized annu- ally in the world's research laboratories [ 185 ] , the number of commercially produced polymers has remained almost ...
Page 152
... mechanical model of a fiber involves the crystallites em- bedded in the " amorphous matrix . " In this case , the crystallite aspect ra- tio has a fundamental influence on the load transfer characteristics and thus the modulus of the ...
... mechanical model of a fiber involves the crystallites em- bedded in the " amorphous matrix . " In this case , the crystallite aspect ra- tio has a fundamental influence on the load transfer characteristics and thus the modulus of the ...
Page 155
... mechanical coupling parallel and perpendicular to the fiber axis . Buckley et al . [ 38 ] have shown that , with oriented polymers , the same mechanical analog describes the mechanical responses in directions parallel and perpendicular ...
... mechanical coupling parallel and perpendicular to the fiber axis . Buckley et al . [ 38 ] have shown that , with oriented polymers , the same mechanical analog describes the mechanical responses in directions parallel and perpendicular ...
Contents
SOLID STATE REACTIONS IN LINEAR | 1 |
CHEMICAL HEALING | 43 |
PRACTICAL ASPECTS OF ADDITIONAL SOLID STATE | 59 |
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acid additional solid amorphous annealing Appl aspect ratio behavior birefringence block temperature chain Chem composites copolyester copolymer courtesy crystallinity crystallization curves decreases deformation degree of crystallinity density diameter diffusion domains Dröscher effect Equation exchange reactions extrusion temperature Fakirov fiber axis fibers drawn filament fracture mechanics fracture toughness function heat of fusion heated element higher increasing initial kg/cm² kinetics linear polycondensates load macromolecules Makromol material matrix maximum measurements mechanical melting point microfibrils microstructure mm/min modulus molded molecules morphology nominal draw ratio noncrystalline nylon 6 fibers nylon 66 orientation parameters peak PET fibers phase Phys polyamides polyesters Polymer Sci polymerization properties Reprinted from Ref samples SAXS Schultz semicrystalline shown in Figure solid state polycondensation solid state post-polycondensation solid state reactions Solid-state extrusion specimen spherulite strength stress structure Table tensile terephthalate thermoplastics toughened transesterification transreactions values x-ray yield Zachmann