Solid State Behavior of Linear Polyesters and Polyamides |
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Page 53
Jerold M. Schultz, Stoyko Fakirov. 1 Nylon 11 177 25.75 2 Nylon 11 yes 161 17.90 3 Nylon 11 160 ° C for 6 hr 177 31.96 4 Nylon 11 yes 160 ° C for 6 hr 161 19.39 5 Nylon 11 180 ° C for 6 hr yes 172 29.67 6 Nylon 11 180 ° C for 6 hr yes ...
Jerold M. Schultz, Stoyko Fakirov. 1 Nylon 11 177 25.75 2 Nylon 11 yes 161 17.90 3 Nylon 11 160 ° C for 6 hr 177 31.96 4 Nylon 11 yes 160 ° C for 6 hr 161 19.39 5 Nylon 11 180 ° C for 6 hr yes 172 29.67 6 Nylon 11 180 ° C for 6 hr yes ...
Page 170
... nylon 6 than in nylon 66 fibers . ( B ) Analysis of loss peak The mechanical - loss - temperature curves of well - conditioned nylon 6 and nylon 66 fibers at 1 % strain amplitude are shown in Figure 22a . A com- parison of two curves ...
... nylon 6 than in nylon 66 fibers . ( B ) Analysis of loss peak The mechanical - loss - temperature curves of well - conditioned nylon 6 and nylon 66 fibers at 1 % strain amplitude are shown in Figure 22a . A com- parison of two curves ...
Page 173
... ( nylon 6 ) = 86 Åand L ( nylon 66 ) = 91 Å . The distribution of the length of the long period L is related to the width of meridional reflection corresponding to the periodicity of ... nylon Melt - Spinning of PET and Nylon Fibers 173.
... ( nylon 6 ) = 86 Åand L ( nylon 66 ) = 91 Å . The distribution of the length of the long period L is related to the width of meridional reflection corresponding to the periodicity of ... nylon Melt - Spinning of PET and Nylon Fibers 173.
Contents
SOLID STATE REACTIONS IN LINEAR | 1 |
CHEMICAL HEALING | 43 |
PRACTICAL ASPECTS OF ADDITIONAL SOLID STATE | 59 |
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acid additional solid amorphous annealing Appl aspect ratio behavior birefringence block temperature chain Chem composites copolyester copolymer courtesy crystallinity crystallization curves decreases deformation degree of crystallinity density diameter diffusion domains Dröscher effect Equation exchange reactions extrusion temperature Fakirov fiber axis fibers drawn filament fracture mechanics fracture toughness function heat of fusion heated element higher increasing initial kg/cm² kinetics linear polycondensates load macromolecules Makromol material matrix maximum measurements mechanical melting point microfibrils microstructure mm/min modulus molded molecules morphology nominal draw ratio noncrystalline nylon 6 fibers nylon 66 orientation parameters peak PET fibers phase Phys polyamides polyesters Polymer Sci polymerization properties Reprinted from Ref samples SAXS Schultz semicrystalline shown in Figure solid state polycondensation solid state post-polycondensation solid state reactions Solid-state extrusion specimen spherulite strength stress structure Table tensile terephthalate thermoplastics toughened transesterification transreactions values x-ray yield Zachmann