Solid State Behavior of Linear Polyesters and Polyamides |
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Page 2
In polymer chemistry they are to be considered both in addition polymerization
and in condensation polymerization . Considerable work has been done in the
field of solid state addition polymerization ( 3 - 8 ] . Considering the solid state ...
In polymer chemistry they are to be considered both in addition polymerization
and in condensation polymerization . Considerable work has been done in the
field of solid state addition polymerization ( 3 - 8 ] . Considering the solid state ...
Page 3
Condensation polymerization , or polycondensation , has been defined by IUPAC
as a polymerization in which small molecules form polymer molecules in a
condensation reaction ; besides polymer molecules , the latter yields other small
...
Condensation polymerization , or polycondensation , has been defined by IUPAC
as a polymerization in which small molecules form polymer molecules in a
condensation reaction ; besides polymer molecules , the latter yields other small
...
Page 70
49 - 32319 ( 1974 ) ( Solid Phase Polymerization of Polyester ) . 76 . Akimoto , N .
, et al . : Japanese Kokai 51 - 73592 ( 1976 ) ( Solid State Postpolymerization of
Poly ( Ethylene Terephthalate ) ) . 77 . Fakirov , S . , et al . : Bulg . Authorship ...
49 - 32319 ( 1974 ) ( Solid Phase Polymerization of Polyester ) . 76 . Akimoto , N .
, et al . : Japanese Kokai 51 - 73592 ( 1976 ) ( Solid State Postpolymerization of
Poly ( Ethylene Terephthalate ) ) . 77 . Fakirov , S . , et al . : Bulg . Authorship ...
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achieved acid additional amorphous annealing Appl applied aspect average behavior block bonding changes Chem chemical composites conclusion constant crack crystallinity crystallization curves decreases deformation density depends determined diameter diffusion direction distribution domains draw ratio drawn effect element energy Equation experiments extrusion factor fatigue fiber Figure fracture fracture toughness function given groups growth healing heat higher important increasing indicated initial length linear load lower material matrix maximum measurements mechanical melt method microfibrils microstructure modulus molded molecular weight molecules nylon nylon 66 observed obtained occurs orientation peak phase Phys polyamides polycondensation polyesters Polymer Sci polymerization properties range reaction regions reported Reprinted from Ref respectively samples SAXS scattering shows solid solid state polycondensation solid-state specimen speed stage strain strength stress structure studied Table temperature tensile units values yield