Solid State Behavior of Linear Polyesters and Polyamides |
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Page 42
The interpretation of the composition vs . time behavior observed was based on
the incorporation of trans units into crystalline regions on the lamellar fold surface
. Furthermore , Lenz and Go [ 36 ] observed that random copolymers of cis - and ...
The interpretation of the composition vs . time behavior observed was based on
the incorporation of trans units into crystalline regions on the lamellar fold surface
. Furthermore , Lenz and Go [ 36 ] observed that random copolymers of cis - and ...
Page 51
Insofar as chemical crosslinking is effective only in the amorphous regions , the
crystalline regions afford some freedom of motion with respect to the defects
incorporated in the crystallites . It can be expected that , during healing , these
defects ...
Insofar as chemical crosslinking is effective only in the amorphous regions , the
crystalline regions afford some freedom of motion with respect to the defects
incorporated in the crystallites . It can be expected that , during healing , these
defects ...
Page 152
... solely by the modulus of the microfibril , which in turn is determined by the
combination of the moduli of the alternating amorphous and crystalline regions
when they are loaded under conditions of equal stress ( i . e . , series load
transfer ) .
... solely by the modulus of the microfibril , which in turn is determined by the
combination of the moduli of the alternating amorphous and crystalline regions
when they are loaded under conditions of equal stress ( i . e . , series load
transfer ) .
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achieved acid additional amorphous annealing Appl applied aspect average behavior block bonding changes Chem chemical composites conclusion constant crack crystallinity crystallization curves decreases deformation density depends determined diameter diffusion direction distribution domains draw ratio drawn effect element energy Equation experiments extrusion factor fatigue fiber Figure fracture fracture toughness function given groups growth healing heat higher important increasing indicated initial length linear load lower material matrix maximum measurements mechanical melt method microfibrils microstructure modulus molded molecular weight molecules nylon nylon 66 observed obtained occurs orientation peak phase Phys polyamides polycondensation polyesters Polymer Sci polymerization properties range reaction regions reported Reprinted from Ref respectively samples SAXS scattering shows solid solid state polycondensation solid-state specimen speed stage strain strength stress structure studied Table temperature tensile units values yield