Solid State Behavior of Linear Polyesters and Polyamides |
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Page 92
... reported as 28.1 and 27.8 cal / g . Multiple melting [ 66 ] and multiple glass transitions [ 14,69 ] have been reported . In analogy with multiple melting behavior in other polymer sys- tems , it is likely that the lower of two melt ...
... reported as 28.1 and 27.8 cal / g . Multiple melting [ 66 ] and multiple glass transitions [ 14,69 ] have been reported . In analogy with multiple melting behavior in other polymer sys- tems , it is likely that the lower of two melt ...
Page 170
... reported for unoriented polymers ( 25 ° C ) and somewhat less than that reported for unconditioned fibers ( 13 ° C ) . The difference in Tg between the unoriented polymers and mechanically conditioned fiber is a very important ...
... reported for unoriented polymers ( 25 ° C ) and somewhat less than that reported for unconditioned fibers ( 13 ° C ) . The difference in Tg between the unoriented polymers and mechanically conditioned fiber is a very important ...
Page 217
... reported by Shimida and Porter in the same paper as the work on PA 6 [ 23 ] . Therefore , most experimental procedures were those reported in chapter 4.1 for PA 6 but for the following : PA 66 was obtained as cylindrical plugs from a ...
... reported by Shimida and Porter in the same paper as the work on PA 6 [ 23 ] . Therefore , most experimental procedures were those reported in chapter 4.1 for PA 6 but for the following : PA 66 was obtained as cylindrical plugs from a ...
Contents
SOLID STATE REACTIONS IN LINEAR | 1 |
CHEMICAL HEALING | 43 |
PRACTICAL ASPECTS OF ADDITIONAL SOLID STATE | 59 |
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acid additional solid amorphous annealing Appl aspect ratio behavior birefringence block temperature chain Chem composites copolyester copolymer courtesy crystallinity crystallization curves decreases deformation degree of crystallinity density diameter diffusion domains Dröscher effect Equation exchange reactions extrusion temperature Fakirov fiber axis fibers drawn filament fracture mechanics fracture toughness function heat of fusion heated element higher increasing initial kg/cm² kinetics linear polycondensates load macromolecules Makromol material matrix maximum measurements mechanical melting point microfibrils microstructure mm/min modulus molded molecules morphology nominal draw ratio noncrystalline nylon 6 fibers nylon 66 orientation parameters peak PET fibers phase Phys polyamides polyesters Polymer Sci polymerization properties Reprinted from Ref samples SAXS Schultz semicrystalline shown in Figure solid state polycondensation solid state post-polycondensation solid state reactions Solid-state extrusion specimen spherulite strength stress structure Table tensile terephthalate thermoplastics toughened transesterification transreactions values x-ray yield Zachmann