Solid State Behavior of Linear Polyesters and Polyamides |
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Page 4
... represents the fraction of the initially present functional groups that have undergone reaction at a certain moment ... represented in these two ways : M1 M1 M1 + M1 M2 M2 M3 M4 ... ( 6 ) and M4 My Mi M1 M6 M13 M24 ... where 4 Solid ...
... represents the fraction of the initially present functional groups that have undergone reaction at a certain moment ... represented in these two ways : M1 M1 M1 + M1 M2 M2 M3 M4 ... ( 6 ) and M4 My Mi M1 M6 M13 M24 ... where 4 Solid ...
Page 85
... represent themselves a significant extended defect . Predecki and Statton have constructed models of the structure of a ny ... represents the state of a crystal in which ( 1 ) all chain ends have been incorporated and ( 2 ) no additional ...
... represent themselves a significant extended defect . Predecki and Statton have constructed models of the structure of a ny ... represents the state of a crystal in which ( 1 ) all chain ends have been incorporated and ( 2 ) no additional ...
Page 105
... represents scat- tering normal to the fiber axis - i.e . , correlations normal to the chain axis . RDF peaks representing atomic separations below 3Å arise from intrachain correlations , those between 3 and 5Å from both intra- and ...
... represents scat- tering normal to the fiber axis - i.e . , correlations normal to the chain axis . RDF peaks representing atomic separations below 3Å arise from intrachain correlations , those between 3 and 5Å from both intra- and ...
Contents
SOLID STATE REACTIONS IN LINEAR | 1 |
CHEMICAL HEALING | 43 |
PRACTICAL ASPECTS OF ADDITIONAL SOLID STATE | 59 |
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acid additional solid amorphous annealing Appl aspect ratio behavior birefringence block temperature chain Chem composites copolyester copolymer courtesy crystallinity crystallization curves decreases deformation degree of crystallinity density diameter diffusion domains Dröscher effect Equation exchange reactions extrusion temperature Fakirov fiber axis fibers drawn filament fracture mechanics fracture toughness function heat of fusion heated element higher increasing initial kg/cm² kinetics linear polycondensates load macromolecules Makromol material matrix maximum measurements mechanical melting point microfibrils microstructure mm/min modulus molded molecules morphology nominal draw ratio noncrystalline nylon 6 fibers nylon 66 orientation parameters peak PET fibers phase Phys polyamides polyesters Polymer Sci polymerization properties Reprinted from Ref samples SAXS Schultz semicrystalline shown in Figure solid state polycondensation solid state post-polycondensation solid state reactions Solid-state extrusion specimen spherulite strength stress structure Table tensile terephthalate thermoplastics toughened transesterification transreactions values x-ray yield Zachmann