Solid State Behavior of Linear Polyesters and Polyamides |
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Page 142
4 ( 2 ) where A is the measured birefringence , X is the volume crystallinity , fc
and fa are the crystalline and amorphous orientation functions , respectively , and
Delta ? and Delta , are the intrinsic birefringences of segments in the crystalline ...
4 ( 2 ) where A is the measured birefringence , X is the volume crystallinity , fc
and fa are the crystalline and amorphous orientation functions , respectively , and
Delta ? and Delta , are the intrinsic birefringences of segments in the crystalline ...
Page 178
... respectively , and those of the scaled - up process by T2 ( t ) and dV2 ( t ) / dz
for t = 0 - tp , the hypothesis was that , if Ti ( t ) = Tz ( t ) ( 23a ) and dVi ( t ) / dz =
dV2 ( t ) / dz ( 236 ) then J1 = 12 The foundation for this hypothesis is the idea that
...
... respectively , and those of the scaled - up process by T2 ( t ) and dV2 ( t ) / dz
for t = 0 - tp , the hypothesis was that , if Ti ( t ) = Tz ( t ) ( 23a ) and dVi ( t ) / dz =
dV2 ( t ) / dz ( 236 ) then J1 = 12 The foundation for this hypothesis is the idea that
...
Page 322
... VS - glass fiber and sphere volume fraction , respectively Wp , ws - glass fiber
and sphere weight fraction , respectively INDEX UNIVERSITY OF MICHIGAN 3
9015 01769 8856 322 Solid State Behavior of Linear Polyesters and Polyamides.
... VS - glass fiber and sphere volume fraction , respectively Wp , ws - glass fiber
and sphere weight fraction , respectively INDEX UNIVERSITY OF MICHIGAN 3
9015 01769 8856 322 Solid State Behavior of Linear Polyesters and Polyamides.
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achieved acid additional amorphous annealing Appl applied aspect average behavior block bonding changes Chem chemical composites conclusion constant crack crystallinity crystallization curves decreases deformation density depends determined diameter diffusion direction distribution domains draw ratio drawn effect element energy Equation experiments extrusion factor fatigue fiber Figure fracture fracture toughness function given groups growth healing heat higher important increasing indicated initial length linear load lower material matrix maximum measurements mechanical melt method microfibrils microstructure modulus molded molecular weight molecules nylon nylon 66 observed obtained occurs orientation peak phase Phys polyamides polycondensation polyesters Polymer Sci polymerization properties range reaction regions reported Reprinted from Ref respectively samples SAXS scattering shows solid solid state polycondensation solid-state specimen speed stage strain strength stress structure studied Table temperature tensile units values yield