Solid State Behavior of Linear Polyesters and Polyamides |
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Page 1
... healing - healing as a result of solid state reaction in linear polycondensates resulting to bonding polymer chains at the interface much below the melting temperature . The predominant role of chemical healing , in 1.
... healing - healing as a result of solid state reaction in linear polycondensates resulting to bonding polymer chains at the interface much below the melting temperature . The predominant role of chemical healing , in 1.
Page 17
... result from ex- change reactions between two polycondensates ( A1B1 ) , and ( A2B2 ) q , are characterized by identical concentrations of A1 and B1 units . Furthermore , this theoretical approach enables one to calculate the degree of ...
... result from ex- change reactions between two polycondensates ( A1B1 ) , and ( A2B2 ) q , are characterized by identical concentrations of A1 and B1 units . Furthermore , this theoretical approach enables one to calculate the degree of ...
Page 55
... result of interchain transreactions , involving ester - ester or amide - amide groups . The established fact that higher heat treatment temperatures corre- spond to higher interface shear stress values may also be interpreted as " more ...
... result of interchain transreactions , involving ester - ester or amide - amide groups . The established fact that higher heat treatment temperatures corre- spond to higher interface shear stress values may also be interpreted as " more ...
Contents
SOLID STATE REACTIONS IN LINEAR | 1 |
CHEMICAL HEALING | 43 |
PRACTICAL ASPECTS OF ADDITIONAL SOLID STATE | 59 |
Copyright | |
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acid additional solid amorphous annealing Appl aspect ratio behavior birefringence block temperature chain Chem composites copolyester copolymer courtesy crystallinity crystallization curves decreases deformation degree of crystallinity density diameter diffusion domains Dröscher effect Equation exchange reactions extrusion temperature Fakirov fiber axis fibers drawn filament fracture mechanics fracture toughness function heat of fusion heated element higher increasing initial kg/cm² kinetics linear polycondensates load macromolecules Makromol material matrix maximum measurements mechanical melting point microfibrils microstructure mm/min modulus molded molecules morphology nominal draw ratio noncrystalline nylon 6 fibers nylon 66 orientation parameters peak PET fibers phase Phys polyamides polyesters Polymer Sci polymerization properties Reprinted from Ref samples SAXS Schultz semicrystalline shown in Figure solid state polycondensation solid state post-polycondensation solid state reactions Solid-state extrusion specimen spherulite strength stress structure Table tensile terephthalate thermoplastics toughened transesterification transreactions values x-ray yield Zachmann