Solid State Behavior of Linear Polyesters and Polyamides |
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Page 46
... values for the critical contact length le were calculated ( for samples Nos . 3 , 5 , and 7 , the T value of sample No. 4 was used , Table 10 ) . The results are also presented in Table 10. Taking into account that these very close 1.
... values for the critical contact length le were calculated ( for samples Nos . 3 , 5 , and 7 , the T value of sample No. 4 was used , Table 10 ) . The results are also presented in Table 10. Taking into account that these very close 1.
Page 54
... values than those with lower crystallinity ( under identical heal- ing conditions ) ( Table 12 , compare samples 1 and 2 , 7 and 8 , 9 and 10 ) . Furthermore , crosslinked nylon 11 samples showed larger σ ; values than the non ...
... values than those with lower crystallinity ( under identical heal- ing conditions ) ( Table 12 , compare samples 1 and 2 , 7 and 8 , 9 and 10 ) . Furthermore , crosslinked nylon 11 samples showed larger σ ; values than the non ...
Page 89
... values of the DC . Similarly , the incorporation of large defect concentrations into the crystal phase must lower the effective heat of fusion and will decrease the intensity of x - ray diffraction . This means that DC measurements ...
... values of the DC . Similarly , the incorporation of large defect concentrations into the crystal phase must lower the effective heat of fusion and will decrease the intensity of x - ray diffraction . This means that DC measurements ...
Contents
SOLID STATE REACTIONS IN LINEAR | 1 |
TRANSREACTIONS AND POSTADDITIONAL | 19 |
CHEMICAL HEALING | 43 |
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acid additional solid amorphous annealing Appl aspect ratio behavior birefringence block temperature chain Chem chemical healing composites copolyester copolymer courtesy crystallinity crystallization curves decreases deformation degree of crystallinity density diameter diffusion domains effect Equation exchange reactions extrusion temperature Fakirov fiber axis fibers drawn filament fracture mechanics fracture toughness function heat of fusion heated element higher increasing initial kg/cm² kinetics linear polycondensates macromolecules Makromol material matrix maximum measurements mechanical melting point microfibrils microstructure mm/min modulus molding molecules morphology nominal draw ratio noncrystalline nylon 6 fibers nylon 66 orientation parameters peak PET fibers phase Phys polyamides polyesters Polymer Sci polymerization properties Reprinted from Ref samples SAXS Schultz semicrystalline shown in Figure solid state polycondensation solid state post-polycondensation solid state reactions Solid-state extrusion specimen spherulite strength stress structure Table tensile terephthalate thermoplastics toughened transesterification transreactions values x-ray yield Zachmann