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Page 199
... equation of state is ( p + 1/2 ) ( V − b ) = RT , ( 43 ) written for one mole of gas . This is an empirical2 equation with two constants , a and b . We can rewrite ( 43 ) for n moles of gas if we substitute n2a for a ; nb for b ; and ...
... equation of state is ( p + 1/2 ) ( V − b ) = RT , ( 43 ) written for one mole of gas . This is an empirical2 equation with two constants , a and b . We can rewrite ( 43 ) for n moles of gas if we substitute n2a for a ; nb for b ; and ...
Page 334
... equation . The van der Waals equation of state was introduced in Problem 12.2 . When written for n moles of molecules the equation is [ p + a ( ~ ) 2 ] V − nb ) = n ᎡᎢ . ( 34 ) We define the quantities a Pc = ; V = 3nb ; 8a RTC ...
... equation . The van der Waals equation of state was introduced in Problem 12.2 . When written for n moles of molecules the equation is [ p + a ( ~ ) 2 ] V − nb ) = n ᎡᎢ . ( 34 ) We define the quantities a Pc = ; V = 3nb ; 8a RTC ...
Page 418
... equation of state , 199 , 334 thermodynamic potential , 337 van't Hoff relation , 350 Vaporization , latent heat , 328 Vapor pressure , 327 equation , 329 manometer , 134 Velocities , molecular ( table ) , 206 Velocity , critical , 290 ...
... equation of state , 199 , 334 thermodynamic potential , 337 van't Hoff relation , 350 Vaporization , latent heat , 328 Vapor pressure , 327 equation , 329 manometer , 134 Velocities , molecular ( table ) , 206 Velocity , critical , 290 ...
Contents
QUANTUM STATES | 1 |
AN ELEMENTARY SOLUBLE SYSTEM | 9 |
THE FUNDAMENTAL ASSUMPTION | 27 |
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absolute zero Boltzmann bosons calculated Carnot cycle chemical potential cm³ combined system concentration curve defined definition denote density derivative diffusive contact dipole distribution function electric field electron energy levels ensemble entropy equal equation ergs example expansion experimental Fermi energy Fermi gas Fermi-Dirac fermions Figure fluctuations fractional free energy free particle frequency given grand sum ground orbital He¹ He³ heat capacity helium ideal gas ideal gas law integral interaction isothermal kinetic lattice liquid low temperatures m₁ magnetic field magnetic moment model system molecule N₁ number of atoms number of particles obtain occupied P₁ partition function phase photons plotted pressure probable configuration Problem properties quantity quantum number relation reservoir result solid spin excess superfluid system in thermal term thermal average thermal contact thermodynamic potential total number U₁ unit vapor velocity versus volume white dwarf ат