Physical Principles and Techniques of Protein ChemistrySydney J. Leach Physical Principles and Techniques of Protein Chemistry Part C ... |
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Page 78
... effect in L - alanine is given by Marsh and Donohue ( 1967 ) . The effect of disorder on a Fourier synthesis is illustrated in Fig . 13 and it will be seen that an increase in B leads to a reduction in the effective resolution . In ...
... effect in L - alanine is given by Marsh and Donohue ( 1967 ) . The effect of disorder on a Fourier synthesis is illustrated in Fig . 13 and it will be seen that an increase in B leads to a reduction in the effective resolution . In ...
Page 127
... effects would then take the same path from the a - carbon atom . In agree- ment with this hypothesis , the ratio of the effect of deprotonation of the carboxyl group to the effect of deprotonation of the NH3 + group appears to be ...
... effects would then take the same path from the a - carbon atom . In agree- ment with this hypothesis , the ratio of the effect of deprotonation of the carboxyl group to the effect of deprotonation of the NH3 + group appears to be ...
Page 128
... effect mediated by the solvent proper and therefore affected by ionic strength . ( 5 ) An inductive effect through the covalent bonds of the protein . ( 6 ) An alteration in the water struc- ture ( electrostrictive changes ) near the ...
... effect mediated by the solvent proper and therefore affected by ionic strength . ( 5 ) An inductive effect through the covalent bonds of the protein . ( 6 ) An alteration in the water struc- ture ( electrostrictive changes ) near the ...
Contents
Electron Microscopy | 2 |
Ultraviolet Absorption | 3 |
Dielectric Properties of Proteins | 7 |
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absorption absorption spectrum amino acids applied atoms axis Biochem Biol Biophys birefringence boundary bovine serum albumin buffer calculated Cann cell Chem chromophores coefficient components concentration curve Debye denaturation density determined dielectric constant dielectric increment dielectric relaxation difference spectrum dipole moment Edelhoch effects electric birefringence electric field electron microscope electrophoresis elution volume emission enzyme equation equilibrium excitation experimental film fluorescence fraction frequency gel filtration gradient groups instrument intensity interactions ionic strength ions lens light linear macromolecules magnification measured method micrographs migration mobility molar molecular weight molecules moving-boundary observed obtained optical ovalbumin parameter particles peaks permanent dipole perturbation phase phenolic photomultiplier Phys plot polarization polymer produced protein quantum yield ratio reaction relaxation residues resolution resolving power ribonuclease scattering shadow shown in Fig solution solvent specimen spectra structure studies technique temperature theoretical theory tion tryptophan tyrosine values wavelength Weber Winzor zone