Elastomeric Polymer NetworksLooking at recent advances in the area of elastomers and rubber-like elasticity, this monograph reviews and evaluates existing elastomers and presents some new results. |
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Page 50
... sliplink can slide a contour length a along the chains . In Eq . ( 5.44 ) T is the slip variable and is a measure for the arc length of sliding compared to the chain length L ( i.e. , the arc length between two crosslinks ) . The length ...
... sliplink can slide a contour length a along the chains . In Eq . ( 5.44 ) T is the slip variable and is a measure for the arc length of sliding compared to the chain length L ( i.e. , the arc length between two crosslinks ) . The length ...
Page 51
... sliplink hardens , but the ʼn suggests softening . This result is reasonable if one accounts for the increase of phase space during deformation for the slip- page a . The slipping distance will be increased and more conformations will ...
... sliplink hardens , but the ʼn suggests softening . This result is reasonable if one accounts for the increase of phase space during deformation for the slip- page a . The slipping distance will be increased and more conformations will ...
Page 55
James E. Mark, Burak Erman. Neutron Scattering in the Sliplink Model A similar replica calculation for the form factor of sliplinks will be very difficult in general , but on a simpler level we can work at the same level as the sliplink ...
James E. Mark, Burak Erman. Neutron Scattering in the Sliplink Model A similar replica calculation for the form factor of sliplinks will be very difficult in general , but on a simpler level we can work at the same level as the sliplink ...
Contents
Recollections of Eugene Guth | 1 |
Microscopic Theory of Rubber Elasticity | 12 |
The Free Energy of an Entangled Network | 20 |
Copyright | |
17 other sections not shown
Common terms and phrases
affine atoms average behavior bond calculated Chem chemical classical configurations constant constraints covalent covalent bonds crosslink density curves deformation dynamics effects elastomers entropy equation Erman Eugene Guth experimental experiments extension ratio extents of reaction Figure force form factor free energy function Gaussian gel point H. M. James interactions intramolecular reaction isotropic J. E. Mark James and Guth James-Guth junction fluctuations Kuhn Kuhn segments lattice length linear localization model loops Macromolecules microscopic molar mass molecular weight molecules monomers motion nematic network chains neutron scattering obtained order parameter orientation P. J. Flory phantom network phase Phys polymer melts Polymer Networks polymerization pr.c predictions properties regime relaxation reptation Rouse model rubber elasticity S. F. Edwards sample segments simulations sliplink statistical strain stress stress-strain stretching structure temperature term theory of rubber thermoelastic tion tube uniaxial values vector Vilgis