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Page 199
... equation of state is ( p a - + √2 ) ( V − b ) = RT , ( 43 ) written for one mole of gas . This is an empirical2 equation with two constants , a and b . We can rewrite ( 43 ) for n moles of gas if we substitute n2a for a ; nb for b ...
... equation of state is ( p a - + √2 ) ( V − b ) = RT , ( 43 ) written for one mole of gas . This is an empirical2 equation with two constants , a and b . We can rewrite ( 43 ) for n moles of gas if we substitute n2a for a ; nb for b ...
Page 334
... equation . The van der Waals equation of state was introduced in Problem 12.2 . When written for n moles of molecules the equation is [ p + a ( ~ ) 2 ] ( V − nb ) = nRT . We define the quantities - . ( 34 ) a Pc = Vc = 3nb ; RTc 27b2 ...
... equation . The van der Waals equation of state was introduced in Problem 12.2 . When written for n moles of molecules the equation is [ p + a ( ~ ) 2 ] ( V − nb ) = nRT . We define the quantities - . ( 34 ) a Pc = Vc = 3nb ; RTc 27b2 ...
Page 418
... equation of state , 199 , 334 thermodynamic potential , 337 van't Hoff relation , 350 Vaporization , latent heat , 328 Vapor pressure , 327 equation , 329 manometer , 134 Velocities , molecular ( table ) , 206 Velocity , critical , 290 ...
... equation of state , 199 , 334 thermodynamic potential , 337 van't Hoff relation , 350 Vaporization , latent heat , 328 Vapor pressure , 327 equation , 329 manometer , 134 Velocities , molecular ( table ) , 206 Velocity , critical , 290 ...
Contents
STATES OF THE MODEL SYSTEM | 11 |
AN ELEMENTARY SOLUBLE SYSTEM | 17 |
SHARP PEAK OF gN | 19 |
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approximation Boltzmann bosons calculated Carnot cycle chemical potential classical regime closed system cm³ combined system concentration defined definition denote derivative diffusive contact dipole distribution function electric field electron energy levels ensemble entropy equal equation equilibrium ergs example expansion experimental Fermi energy Fermi gas Fermi-Dirac fermions Figure fluctuations flux fractional free energy free particle frequency gases given grand sum He¹ He³ heat capacity helium ideal gas law increase integral isothermal kinetic lattice liquid low temperature m₁ magnetic field magnetic moment model system molecule N₁ negative temperature number of accessible number of atoms number of particles occupied P₁ partition function photons plotted pressure probable configuration Problem properties quantity quantum number reservoir result spin excess superfluid system in thermal term thermal average thermal contact thermodynamic potential total number U₁ unit velocity versus volume white dwarf ат