Mechanism and Theory in Organic Chemistry

acetic acid addition alkene alkyl American Chemical Society Angew anion antarafacial aromatic atoms base benzene biradical butadiene carbanion carbon carbonyl catalysis cation CH₂ CH3 CH3 CH3 H Chem Chemistry compounds configuration conjugate conrotatory correlation cycloaddition cyclopropyl diagram double bond electron electrophilic elimination energy equilibrium example excited Figure formed G. A. Olah H CH3 H H H H. C. Brown H₂O hydrogen interaction intermediate ion pair ionization isotope effect J. K. Kochi k₁ kcal kcal mole-1 ketones kinetic leaving group LUMO mechanism methyl mole-¹ molecular orbitals molecule nucleophile occur percent phenyl Phys proton R₁ rate constant rate-determining rate-determining step reactants reaction coordinate reactive rearrangement resonance ring Scheme Schleyer shown in Equation singlet solution solvation solvent solvolysis stabilization step stereochemistry steric Streitwieser structure substituents substitution substrate symmetry syn elimination Table Tetrahedron Lett tion tosylate transfer transition triplet Wiley Winstein York